Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

Base Information

Chemical Name:Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester
CAS No.:913625-11-3
Molecular Formula:C₃₁H₄₀O₁₉S
Molecular Weight:748.713
Hs Code.:

Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

Synonyms:Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

Suppliers and Price of Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

There total 1 articles about Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 120852-02-0
Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-((2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester

: 98-59-9
p-toluenesulfonyl chloride

: 913625-11-3
Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

Guidance literature:: With 1,4-diaza-bicyclo[2.2.2]octane; In dichloromethane; at 0 ℃; for 45h;
DOI:10.1016/j.bmc.2006.06.034

Reference yield: 100.0%

: 913625-11-3
Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

: 108-24-7
acetic anhydride

: 913625-12-4
Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4,5-triacetoxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

Guidance literature:: With pyridine; at 20 ℃;
DOI:10.1016/j.bmc.2006.06.034

Reference yield:

: 913625-11-3
Acetic acid (3R,4S,5R,6R)-2,3-diacetoxy-6-acetoxymethyl-5-[(2S,3R,4S,5S,6R)-3,4-diacetoxy-5-hydroxy-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

: 2-{4-[(2,4-diamino-pteridin-6-ylmethyl)-methyl-amino]-benzoylamino}-4-{2-[6-(6-fluoro-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-3,4,5-trihydroxy-tetrahydro-pyran-2-ylmethylsulfanyl]-ethylcarbamoyl}-butyric acid methyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: 100 percent / pyridine / 20 °C

2.1: potassium tert-butoxide / tetrahydrofuran / 2 h / 20 °C

2.2: pyridine / tetrahydrofuran

3.1: 244 mg / trifluoroacetic acid / CH₂Cl₂ / 1 h / 20 °C

4.1: 49 percent / (benzotriazol-1-yl-oxy)tripyrrolidinophosphonium PF₆; ethyldiisopropylamine / CH₂Cl₂; dimethylformamide / 20 °C

5.1: 52 percent / HF; pyridine / 2 h / 20 °C

6.1: 40 percent / lithium hydroxide monohydrate / H₂O; methanol / 6 h / 20 °C

With pyridine; lithium hydroxide; hydrogen fluoride; potassium tert-butylate; benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2006.06.034