(2,4-dimethyl-4-pentyl-cyclohexa-1,5-dienyloxy)-triisopropyl-silane

Base Information

• Chemical Name: (2,4-dimethyl-4-pentyl-cyclohexa-1,5-dienyloxy)-triisopropyl-silane
• CAS No.: 779348-88-8
• Molecular Formula: C₂₂H₄₂OSi
• Molecular Weight: 350.66
• Mol file: 779348-88-8.mol

Synonyms:(2,4-dimethyl-4-pentyl-cyclohexa-1,5-dienyloxy)-triisopropyl-silane

Chemical Property of (2,4-dimethyl-4-pentyl-cyclohexa-1,5-dienyloxy)-triisopropyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,4-dimethyl-4-pentyl-cyclohexa-1,5-dienyloxy)-triisopropyl-silane

There total 2 articles about (2,4-dimethyl-4-pentyl-cyclohexa-1,5-dienyloxy)-triisopropyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Triisopropyl-[3-methyl-3-(2-methyl-allyl)-oct-1-ynyloxy]-silane (779348-86-6) → (2,4-dimethyl-4-pentyl-cyclohexa-1,5-dienyloxy)-triisopropyl-silane (779348-88-8)

Guidance literature:

With gold(I) chloride; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1021/ja046112y

Reference yield:

triisopropylsilyl trifluoromethanesulfonate (80522-42-5) → (2,4-dimethyl-4-pentyl-cyclohexa-1,5-dienyloxy)-triisopropyl-silane (779348-88-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: LiHMDS; t-BuOOLi / tetrahydrofuran; toluene / 2.5 h / -78 - 0 °C

1.2: 70 percent / tetrahydrofuran; toluene / -78 - 0 °C

2.1: 88 percent / AuCl / CH₂Cl₂ / 0.5 h / 20 °C

With lithium tert-butyl hydroperoxide; lithium hexamethyldisilazane; gold(I) chloride; In tetrahydrofuran; dichloromethane; toluene;

DOI:10.1021/ja063384n

Reference yield: 91.0%

(2,4-dimethyl-4-pentyl-cyclohexa-1,5-dienyloxy)-triisopropyl-silane (779348-88-8) → 4,6-dimethyl-4-pentyl-cyclohex-2-enone

Guidance literature:

With hydrogenchloride; In acetonitrile; for 1h;

DOI:10.1021/ja046112y

upstream raw materials:

Triisopropyl-[3-methyl-3-(2-methyl-allyl)-oct-1-ynyloxy]-silane

triisopropylsilyl trifluoromethanesulfonate