(SS,2S,3R)-2-cyclohexylsulfinyl-N,N-dimethyl-3-methylpent-4-enethioamide

Base Information

Chemical Name:(SS,2S,3R)-2-cyclohexylsulfinyl-N,N-dimethyl-3-methylpent-4-enethioamide
CAS No.:385837-76-3
Molecular Formula:C₁₄H₂₅NOS₂
Molecular Weight:287.491
Hs Code.:

Synonyms:(SS,2S,3R)-2-cyclohexylsulfinyl-N,N-dimethyl-3-methylpent-4-enethioamide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (SS,2S,3R)-2-cyclohexylsulfinyl-N,N-dimethyl-3-methylpent-4-enethioamide

Chemical Property:

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Technology Process of (SS,2S,3R)-2-cyclohexylsulfinyl-N,N-dimethyl-3-methylpent-4-enethioamide

There total 5 articles about (SS,2S,3R)-2-cyclohexylsulfinyl-N,N-dimethyl-3-methylpent-4-enethioamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 41719-04-4
Cyclohexanesulfinyl chloride

: 385837-76-3
(SS,2S,3R)-2-cyclohexylsulfinyl-N,N-dimethyl-3-methylpent-4-enethioamide

Guidance literature:: Multi-step reaction with 4 steps

1.1: 83 percent / pyridine / tetrahydrofuran / 2.5 h / -50 °C

2.1: NaHMDS / tetrahydrofuran / 1.5 h / -78 °C

3.1: t-BuLi / tetrahydrofuran; pentane / -40 - 0 °C

3.2: tetrahydrofuran; pentane / -40 - 20 °C

4.1: 202 mg / tetrahydrofuran; pentane / 2.5 h / 66 °C

With pyridine; tert.-butyl lithium; sodium hexamethyldisilazane; In tetrahydrofuran; pentane; 4.1: Claisen rearrangement;
DOI:10.1021/jo015956m

Reference yield:

: 226709-30-4
(R)-2-(Cyclohexylsulfinyl)-N,N-dimethylethanethioamide

: 385837-76-3
(SS,2S,3R)-2-cyclohexylsulfinyl-N,N-dimethyl-3-methylpent-4-enethioamide

Guidance literature:: Multi-step reaction with 2 steps

1.1: t-BuLi / tetrahydrofuran; pentane / -40 - 0 °C

1.2: tetrahydrofuran; pentane / -40 - 20 °C

2.1: 202 mg / tetrahydrofuran; pentane / 2.5 h / 66 °C

With tert.-butyl lithium; In tetrahydrofuran; pentane; 2.1: Claisen rearrangement;
DOI:10.1021/jo015956m

Reference yield:

: 220972-34-9
1,2:5,6-di-O-isopropylidene-α-D-glucofuranosyl (S)-cyclohexanesulfinate

: 385837-76-3
(SS,2S,3R)-2-cyclohexylsulfinyl-N,N-dimethyl-3-methylpent-4-enethioamide

Guidance literature:: Multi-step reaction with 3 steps

1.1: NaHMDS / tetrahydrofuran / 1.5 h / -78 °C

2.1: t-BuLi / tetrahydrofuran; pentane / -40 - 0 °C

2.2: tetrahydrofuran; pentane / -40 - 20 °C

3.1: 202 mg / tetrahydrofuran; pentane / 2.5 h / 66 °C

With tert.-butyl lithium; sodium hexamethyldisilazane; In tetrahydrofuran; pentane; 3.1: Claisen rearrangement;
DOI:10.1021/jo015956m