trans-acetonitrilebis{1,2-bis(diphenylphosphino)ethane}nitridomolybdenum(IV) tetraphenylborate

Base Information

• Chemical Name: trans-acetonitrilebis{1,2-bis(diphenylphosphino)ethane}nitridomolybdenum(IV) tetraphenylborate
• CAS No.: 120751-78-2
• Molecular Formula: C₂₄H₂₀B*C₅₄H₅₁MoN₂P₄
• Molecular Weight: 1267.08
• Mol file: 120751-78-2.mol

Synonyms:trans-acetonitrilebis{1,2-bis(diphenylphosphino)ethane}nitridomolybdenum(IV) tetraphenylborate

Chemical Property of trans-acetonitrilebis{1,2-bis(diphenylphosphino)ethane}nitridomolybdenum(IV) tetraphenylborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-acetonitrilebis{1,2-bis(diphenylphosphino)ethane}nitridomolybdenum(IV) tetraphenylborate

There total 2 articles about trans-acetonitrilebis{1,2-bis(diphenylphosphino)ethane}nitridomolybdenum(IV) tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Mo(NNC5H10)(dppe)2] + triethylammonium tetraphenylborate + acetonitrile (75-05-8,26809-02-9) → piperidine (110-89-4) + trans-acetonitrilebis{1,2-bis(diphenylphosphino)ethane}nitridomolybdenum(IV) tetraphenylborate (120751-78-2) + triethylamine (121-44-8)

Guidance literature:

In acetonitrile; N2 atmosphere; 25°C (stopped-flow apparatus); spectrophotometric detection; Kinetics;

DOI:10.1039/DT9890000425

Reference yield:

trans-{Mo(NH)Cl(Ph2PCH2CH2PPh2)2}Cl + sodium tetraphenyl borate (143-66-8) + triethylamine (121-44-8) + acetonitrile (75-05-8,26809-02-9) → trans-acetonitrilebis{1,2-bis(diphenylphosphino)ethane}nitridomolybdenum(IV) tetraphenylborate (120751-78-2) + triethylammonium tetraphenylborate

Guidance literature:

In acetonitrile; byproducts: NaCl; N2 atmosphere; addn. of NaBPh4 and NEt3 to soln. of Mo-complex (stirring), stirring (room temp., 0.5 h); concn. (vac.), removal of ppt. of NaCl (filtration), cryst. on diethyl ether addn. and standing (several hours), filtration off, washing (ice-cold acetonitrile, diethyl ether), drying (vac.);

DOI:10.1039/DT9890000425

Reference yield:

trans-acetonitrilebis{1,2-bis(diphenylphosphino)ethane}nitridomolybdenum(IV) tetraphenylborate (120751-78-2) + lutidinium tetraphenylborate → [Mo(NH)(acetonitrile)(dppe)2](BPh4)2

Guidance literature:

In acetonitrile; monitored by UV/vis; not isolated;

DOI:10.1021/ic060141n

upstream raw materials:

sodium tetraphenyl borate

triethylamine

acetonitrile