trityl tetrakis(3,5-dichlorophenyl)borate

Base Information

• Chemical Name: trityl tetrakis(3,5-dichlorophenyl)borate
• CAS No.: 1407533-00-9
• Molecular Formula: C₁₉H₁₅*C₂₄H₁₂BCl₈
• Molecular Weight: 838.122
• Mol file: 1407533-00-9.mol

Synonyms:trityl tetrakis(3,5-dichlorophenyl)borate

Chemical Property of trityl tetrakis(3,5-dichlorophenyl)borate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of trityl tetrakis(3,5-dichlorophenyl)borate

There total 1 articles about trityl tetrakis(3,5-dichlorophenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

trityl chloride (76-83-5) + sodium tetrakis(3,5-dichlorophenyl)borate → trityl tetrakis(3,5-dichlorophenyl)borate (1407533-00-9)

Guidance literature:

In dichloromethane; for 1h; Schlenk technique; Inert atmosphere; Heating;

DOI:10.1002/anie.202011372

Reference yield: 87.6%

[Zr(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)((trimethylsilyl)methyl)3] (1407532-64-2) + trityl tetrakis(3,5-dichlorophenyl)borate (1407533-00-9) → [(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)2][B(3,5-C6H3Cl2)4] (1407532-68-6)

Guidance literature:

In dichloromethane; at 20 ℃; for 3h; Inert atmosphere; Schlenk technique; Darkness;

DOI:10.1021/ic301880z

Reference yield: 85.0%

diethyl ether (60-29-7,927820-24-4) + [nBuTi(N3N)] + trityl tetrakis(3,5-dichlorophenyl)borate (1407533-00-9) → [(Et2O)Ti(N3N)][B(3,5-Cl2C6H3)4]

Guidance literature:

at 24 ℃; for 2h; Schlenk technique; Glovebox; Inert atmosphere;

DOI:10.1039/c7dt04859a

upstream raw materials:

trityl chloride

Downstream raw materials:

[(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)₂][B(3,5-C₆H₃Cl₂)₄]