(2R,4R)-2-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentanal

Base Information

Chemical Name:(2R,4R)-2-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentanal
CAS No.:1431879-78-5
Molecular Formula:C₁₉H₃₂O₃Si
Molecular Weight:336.547
Hs Code.:

Synonyms:(2R,4R)-2-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentanal

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Chemical Property of (2R,4R)-2-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentanal

Chemical Property:

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Technology Process of (2R,4R)-2-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentanal

There total 4 articles about (2R,4R)-2-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1431879-89-8
(2R,4R)-2-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentan-1-ol

: 1431879-78-5
(2R,4R)-2-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentanal

Guidance literature:: With sulfur trioxide pyridine complex; N-ethyl-N,N-diisopropylamine; In dichloromethane; dimethyl sulfoxide; at 0 ℃; for 0.0833333h; Inert atmosphere;
DOI:10.1021/ol400487e

Reference yield:

: 1006724-46-4
(2R,4R)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentane-1,2-diol

: 1431879-78-5
(2R,4R)-2-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentanal

Guidance literature:: Multi-step reaction with 3 steps

1: pyridinium p-toluenesulfonate / dichloromethane / 2 h / 20 °C / Inert atmosphere

2: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / 0 - 20 °C / Inert atmosphere

3: N-ethyl-N,N-diisopropylamine; sulfur trioxide pyridine complex / dichloromethane; dimethyl sulfoxide / 0.08 h / 0 °C / Inert atmosphere

With sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; In dichloromethane; dimethyl sulfoxide; toluene;
DOI:10.1021/ol400487e

Reference yield:

: 1431879-90-1
C₁₉H₃₂O₃Si

: 1431879-78-5
(2R,4R)-2-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-methylpentanal

Guidance literature:: Multi-step reaction with 2 steps

1: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / 0 - 20 °C / Inert atmosphere

2: N-ethyl-N,N-diisopropylamine; sulfur trioxide pyridine complex / dichloromethane; dimethyl sulfoxide / 0.08 h / 0 °C / Inert atmosphere

With sulfur trioxide pyridine complex; diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; In dichloromethane; dimethyl sulfoxide; toluene;
DOI:10.1021/ol400487e