4-ferrocenyl-2,6-diisopropylbromobenzene

Base Information

Chemical Name:4-ferrocenyl-2,6-diisopropylbromobenzene
CAS No.:876125-30-3
Molecular Formula:C₂₂H₂₅BrFe
Molecular Weight:425.191
Hs Code.:

Synonyms:4-ferrocenyl-2,6-diisopropylbromobenzene

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Chemical Property of 4-ferrocenyl-2,6-diisopropylbromobenzene

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Technology Process of 4-ferrocenyl-2,6-diisopropylbromobenzene

There total 1 articles about 4-ferrocenyl-2,6-diisopropylbromobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

: 856197-47-2
2-bromo-5-iodo-1,3-diisopropylbenzene

: 102-54-5,55404-68-7
ferrocene

: 876125-30-3
4-ferrocenyl-2,6-diisopropylbromobenzene

Guidance literature:: With tert-butyllithium; zinc chloride; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; pentane; under Ar atm. to soln. Cp2Fe in THF at -78°C t-BuLi in pentane was added, stirred for 15 min, warmed to 0°C in 30 min, ZnCl2 was added, and stirred for 30 min, suspn. aryliodide and Pd cat. in THF was added, stirred for 12 h, warmed to rt; react. mixt. was concd. in vacuo and purified by column chromy. on silica (hexane) and gel permeation chromy.; elem. anal.;
DOI:10.1021/ic051038l

Reference yield: 34.0%

: 876125-30-3
4-ferrocenyl-2,6-diisopropylbromobenzene

: 182227-72-1
bis(2,4,6-tri-isopropylphenyl)phosphinous chloride

: (4-ferrocenyl-2,6-diisopropylphenyl)bis(2,4,6-triisopropylphenyl)phosphine*0.5ethanol

Guidance literature:: With butyllithium; CuCl; In tetrahydrofuran; hexane; under Ar atm. to ferrocene in THF at -78°C BuLi in hexane was added, stirred for 30 min, CuCl was added, stirred for 30 min, warmed to rt, stirred for 1 h, cooled to -78°C, ClPAr2 in THF was added, stirred for 2 h, refluxed for 12 h; react. mixt. was cooled to room temp., concd. in vacuo and purified by chromy. on alumina (hexane); elem. anal.;
DOI:10.1021/ic051038l