(E)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-2-yl)dimethyl(phenyl)silane

Base Information

Chemical Name:(E)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-2-yl)dimethyl(phenyl)silane
CAS No.:1622446-03-0
Molecular Formula:C₁₉H₂₄O₄SSi
Molecular Weight:376.549
Hs Code.:

Synonyms:(E)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-2-yl)dimethyl(phenyl)silane

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Chemical Property of (E)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-2-yl)dimethyl(phenyl)silane

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Technology Process of (E)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-2-yl)dimethyl(phenyl)silane

There total 4 articles about (E)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-2-yl)dimethyl(phenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 766-77-8
Dimethylphenylsilane

: 1622445-77-5
((3-(methoxymethoxy)prop-1-yn-1-yl)sulfonyl)benzene

: 1622445-78-6
(Z)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-1-yl)dimethyl(phenyl)silane

: 1622446-03-0
(E)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-2-yl)dimethyl(phenyl)silane

Guidance literature:: With C₁₁H₇Co₂O₇; In 1,2-dichloro-ethane; at 60 ℃; for 2h; regioselective reaction;
DOI:10.1002/ejoc.201402577

Reference yield:

: 122647-13-6
(3-(methoxymethoxy)prop-1-yn-1-yl)(phenyl)sulfane

: 1622445-78-6
(Z)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-1-yl)dimethyl(phenyl)silane

: 1622446-03-0
(E)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-2-yl)dimethyl(phenyl)silane

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 0 °C

2: C₁₁H₇Co₂O₇ / 1,2-dichloro-ethane / 2 h / 60 °C

With C₁₁H₇Co₂O₇; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; 1,2-dichloro-ethane;
DOI:10.1002/ejoc.201402577

Reference yield:

: 1212-08-4
S-Phenyl benzenethiosulfonate

: 1622445-78-6
(Z)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-1-yl)dimethyl(phenyl)silane

: 1622446-03-0
(E)-(3-(methoxymethoxy)-1-(phenylsulfonyl)prop-1-en-2-yl)dimethyl(phenyl)silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: 1.5 h / -78 °C

2.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 2 h / 0 °C

3.1: C₁₁H₇Co₂O₇ / 1,2-dichloro-ethane / 2 h / 60 °C

With n-butyllithium; C₁₁H₇Co₂O₇; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; hexane; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1002/ejoc.201402577