cyclobutane-1,1-diylbis(Methylene) bis(4-Methylbenzenesulfonate)

Base Information Edit

Chemical Name:cyclobutane-1,1-diylbis(Methylene) bis(4-Methylbenzenesulfonate)
CAS No.:22308-09-4
Molecular Formula:C20H24 O6 S2
Molecular Weight:424.539
Hs Code.:2902900000
Mol file:22308-09-4.mol

Synonyms:1,1-Cyclobutanedimethanol,bis(4-methylbenzenesulfonate) (9CI); 1,1-Cyclobutanedimethanol, di-p-toluenesulfonate(7CI,8CI); 1,1-Bis[(tosyloxy)methyl]cyclobutane; NSC 378221

Suppliers and Price of cyclobutane-1,1-diylbis(Methylene) bis(4-Methylbenzenesulfonate)

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
CYCLOBUTANE-1,1-DIYLBIS(METHYLENE) BIS-(4-METHYLBENZENESULFONATE) 95.00%
5MG
$ 496.51

Total 4 raw suppliers

Chemical Property of cyclobutane-1,1-diylbis(Methylene) bis(4-Methylbenzenesulfonate) Edit

Chemical Property:

Vapor Pressure:8.02E-13mmHg at 25°C
Boiling Point:579.5°Cat760mmHg
Flash Point:304.3°C
PSA：103.50000
Density:1.289g/cm³
LogP:5.74610

Purity/Quality:

99% ^*data from raw suppliers

CYCLOBUTANE-1,1-DIYLBIS(METHYLENE) BIS-(4-METHYLBENZENESULFONATE) 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of cyclobutane-1,1-diylbis(Methylene) bis(4-Methylbenzenesulfonate)

There total 5 articles about cyclobutane-1,1-diylbis(Methylene) bis(4-Methylbenzenesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 4415-73-0
[1-(hydroxymethyl)cyclobutyl]methanol

: 98-59-9
p-toluenesulfonyl chloride

: 22308-09-4
[1-(p-tolylsulfonyloxymethyl)cyclobutyl]methyl-4-methylbenzenesulfonate

Guidance literature:: With pyridine; at 0 ℃;

Reference yield:

: 5445-51-2
cyclobutane-1,1'-dicarboxylic acid

: 22308-09-4
[1-(p-tolylsulfonyloxymethyl)cyclobutyl]methyl-4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / LiAlH₄ / tetrahydrofuran / 12 h / Heating

2: 77 percent / pyridine / 72 h / 0 °C

With pyridine; lithium aluminium tetrahydride; In tetrahydrofuran;
DOI:10.1021/ja00256a040

Reference yield:

: 3779-29-1
diethyl cyclobutane-1,1-dicarboxylate

: 22308-09-4
[1-(p-tolylsulfonyloxymethyl)cyclobutyl]methyl-4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / LiAlH₄ / tetrahydrofuran / Heating

2: 90 percent / pyridine / 0 °C

With pyridine; lithium aluminium tetrahydride; In tetrahydrofuran;