(2S,3R,9S,13S,14S)-14-((4S,6R)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3,9,13-tris-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-1-phenyl-hexadec-15-ene-1,5,11-trione

Base Information

Chemical Name:(2S,3R,9S,13S,14S)-14-((4S,6R)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3,9,13-tris-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-1-phenyl-hexadec-15-ene-1,5,11-trione
CAS No.:585535-28-0
Molecular Formula:C₅₆H₉₄O₉Si₃
Molecular Weight:995.613
Hs Code.:

(2S,3R,9S,13S,14S)-14-((4S,6R)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3,9,13-tris-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-1-phenyl-hexadec-15-ene-1,5,11-trione

Synonyms:(2S,3R,9S,13S,14S)-14-((4S,6R)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3,9,13-tris-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-1-phenyl-hexadec-15-ene-1,5,11-trione

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Chemical Property of (2S,3R,9S,13S,14S)-14-((4S,6R)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3,9,13-tris-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-1-phenyl-hexadec-15-ene-1,5,11-trione

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Technology Process of (2S,3R,9S,13S,14S)-14-((4S,6R)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3,9,13-tris-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-1-phenyl-hexadec-15-ene-1,5,11-trione

There total 3 articles about (2S,3R,9S,13S,14S)-14-((4S,6R)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3,9,13-tris-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-1-phenyl-hexadec-15-ene-1,5,11-trione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 585535-27-9
C₆₅H₁₁₂O₆S₆Si₃

: 585535-28-0
(2S,3R,9S,13S,14S)-14-((4S,6R)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3,9,13-tris-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-1-phenyl-hexadec-15-ene-1,5,11-trione

Guidance literature:: With bis-[(trifluoroacetoxy)iodo]benzene; In tetrahydrofuran; water;
DOI:10.1021/ol034989g

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 585535-28-0
(2S,3R,9S,13S,14S)-14-((4S,6R)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3,9,13-tris-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-1-phenyl-hexadec-15-ene-1,5,11-trione

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / 2,6-lutidine

2: 67 percent / PhI(O₂CCF₃)2 / tetrahydrofuran; H₂O

With 2,6-dimethylpyridine; bis-[(trifluoroacetoxy)iodo]benzene; In tetrahydrofuran; water;
DOI:10.1021/ol034989g

Reference yield:

: 585535-24-6
1-{2-[3-(6-benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-2-(tert-butyl-dimethyl-silanyloxy)-pent-4-enyl]-[1,3]dithian-2-yl}-5-{2-[2-(tert-butyl-dimethyl-silanyloxy)-3-(2-phenyl-[1,3]dithian-2-yl)-pentyl]-[1,3]dithian-2-yl}-pentan-2-ol

: 585535-28-0
(2S,3R,9S,13S,14S)-14-((4S,6R)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3,9,13-tris-(tert-butyl-dimethyl-silanyloxy)-2-ethyl-1-phenyl-hexadec-15-ene-1,5,11-trione

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / 2,6-lutidine

2: 67 percent / PhI(O₂CCF₃)2 / tetrahydrofuran; H₂O

With 2,6-dimethylpyridine; bis-[(trifluoroacetoxy)iodo]benzene; In tetrahydrofuran; water;
DOI:10.1021/ol034989g