11-(4-nitro-benzoyloxy)-drim-7-ene

Base Information

Chemical Name:11-(4-nitro-benzoyloxy)-drim-7-ene
CAS No.:95138-34-4
Molecular Formula:C₂₂H₂₉NO₄
Molecular Weight:371.477
Hs Code.:

Synonyms:11-(4-nitro-benzoyloxy)-drim-7-ene

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Chemical Property of 11-(4-nitro-benzoyloxy)-drim-7-ene

Chemical Property:

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Technology Process of 11-(4-nitro-benzoyloxy)-drim-7-ene

There total 7 articles about 11-(4-nitro-benzoyloxy)-drim-7-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 468-68-8
(-)-drimenol

: 62-23-7
4-nitro-benzoic acid

: 95138-34-4
11-(4-nitro-benzoyloxy)-drim-7-ene

Guidance literature:: With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃;
DOI:10.1016/j.ejmech.2017.11.051

Reference yield:

: 515-03-7
sclareol

: 95138-34-4
11-(4-nitro-benzoyloxy)-drim-7-ene

Guidance literature:: Multi-step reaction with 5 steps

1.1: potassium permanganate; acetic anhydride / acetone / 0 - 20 °C

2.1: diethyl ether / -78 °C

3.1: acetic anhydride; dihydrogen peroxide; maleic anhydride / dichloromethane; water / 12 h / 20 °C

4.1: sulfuric acid / ethanol / 0 h

4.2: 0.01 h

5.1: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; dmap / dichloromethane / 20 °C

With maleic anhydride; dmap; potassium permanganate; sulfuric acid; dihydrogen peroxide; acetic anhydride; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In diethyl ether; ethanol; dichloromethane; water; acetone; 3.1: |Baeyer-Villiger Ketone Oxidation;
DOI:10.1016/j.ejmech.2017.11.051

Reference yield:

: 564-20-5,1216-84-8,30450-17-0,58976-28-6,64090-92-2,67844-42-2,79768-41-5,79768-42-6,86688-27-9,86688-28-0,95406-08-9,98719-44-9,98719-46-1,131831-65-7,140851-80-5
(3aR)-(+)-sclareolide

: 95138-34-4
11-(4-nitro-benzoyloxy)-drim-7-ene

Guidance literature:: Multi-step reaction with 4 steps

1.1: diethyl ether / -78 °C

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.24 h / Reflux

2.2: 20 °C

3.1: toluene-4-sulfonic acid / dichloromethane / 0 - 17 °C

4.1: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; dmap / dichloromethane / 20 °C

With dmap; toluene-4-sulfonic acid; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; dichloromethane;
DOI:10.1016/j.ejmech.2017.11.051