tricarbonyldicyclohexylphosphine(η(2)-dicyclohexylphosphinito)manganese

Base Information

Chemical Name:tricarbonyldicyclohexylphosphine(η(2)-dicyclohexylphosphinito)manganese
CAS No.:186376-42-1
Molecular Formula:C₂₇H₄₅MnO₃P₂S
Molecular Weight:566.604
Hs Code.:

Synonyms:tricarbonyldicyclohexylphosphine(η(2)-dicyclohexylphosphinito)manganese

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Chemical Property of tricarbonyldicyclohexylphosphine(η(2)-dicyclohexylphosphinito)manganese

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Technology Process of tricarbonyldicyclohexylphosphine(η(2)-dicyclohexylphosphinito)manganese

There total 2 articles about tricarbonyldicyclohexylphosphine(η(2)-dicyclohexylphosphinito)manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 119208-87-6
Tetracarbonyl(η2-dicyclohexylthiophosphinito)mangan(I)

: 78129-68-7
2,2-dimethylpropylidynephosphine

: 186376-42-1
tricarbonyldicyclohexylphosphine(η(2)-dicyclohexylphosphinito)manganese

Guidance literature:: In tetrahydrofuran; byproducts: (C6H11)CPC(C6H11)SP; heating a mixture of 1.35 mmol starting Mn-complex and 3.40 mmol phosphaalkine at 66 ° C for 5 h;; solvent removal; column chromy. (silica, petrol ether); elem. anal.;;

Reference yield:

: 119208-87-6
Tetracarbonyl(η2-dicyclohexylthiophosphinito)mangan(I)

: 101055-70-3
1-adamantylphosphaacetylene

: 186376-42-1
tricarbonyldicyclohexylphosphine(η(2)-dicyclohexylphosphinito)manganese

Guidance literature:: In tetrahydrofuran; Ar-atmosphere; refluxing Mn-complex with excess alkyne for 6 h; solvent removal (vac.), dissoln. in EtOAc/petroleum ether=1:3, filtration, chromy. (SiO2), MPLC (SiO2, EtOAc/petroleum ether=1:3);
DOI:10.1016/S0022-328X(96)06431-5