2-{[2,6-bis(diphenylmethyl)-4-methylphenyl]imino}-1,2-dihydroacenaphthylen-1-one

Base Information

• Chemical Name: 2-{[2,6-bis(diphenylmethyl)-4-methylphenyl]imino}-1,2-dihydroacenaphthylen-1-one
• CAS No.: 1285664-33-6
• Molecular Formula: C₄₅H₃₃NO
• Molecular Weight: 603.763
• Mol file: 1285664-33-6.mol

Synonyms:2-{[2,6-bis(diphenylmethyl)-4-methylphenyl]imino}-1,2-dihydroacenaphthylen-1-one

Chemical Property of 2-{[2,6-bis(diphenylmethyl)-4-methylphenyl]imino}-1,2-dihydroacenaphthylen-1-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-{[2,6-bis(diphenylmethyl)-4-methylphenyl]imino}-1,2-dihydroacenaphthylen-1-one

There total 4 articles about 2-{[2,6-bis(diphenylmethyl)-4-methylphenyl]imino}-1,2-dihydroacenaphthylen-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

2,6-diphenylmethyl-4-methylaniline (56138-96-6) + acenaphthene quinone (82-86-0) → 2-{[2,6-bis(diphenylmethyl)-4-methylphenyl]imino}-1,2-dihydroacenaphthylen-1-one (1285664-33-6)

Guidance literature:

acenaphthene quinone; In acetonitrile; for 1h; Reflux;

With acetic acid; In acetonitrile; Reflux;

2,6-diphenylmethyl-4-methylaniline; In acetonitrile; for 8h; Reflux; Inert atmosphere;

DOI:10.1021/acs.joc.6b02867

Reference yield:

C45H33Cl2NOZn → 2-{[2,6-bis(diphenylmethyl)-4-methylphenyl]imino}-1,2-dihydroacenaphthylen-1-one (1285664-33-6)

Guidance literature:

With potassium oxalate; In dichloromethane; water; for 1h;

DOI:10.1016/j.jorganchem.2018.01.055

Reference yield:

p-toluidine (106-49-0,12221-03-3) → 2-{[2,6-bis(diphenylmethyl)-4-methylphenyl]imino}-1,2-dihydroacenaphthylen-1-one (1285664-33-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: dichloromethane / 120 °C

1.2: 0.5 h / 120 - 160 °C

2.1: toluene-4-sulfonic acid / toluene / 6 h / Reflux

With toluene-4-sulfonic acid; In dichloromethane; toluene;

DOI:10.1021/jacs.0c06644

upstream raw materials:

2,6-diphenylmethyl-4-methylaniline

acenaphthene quinone

p-toluidine

1,1-Diphenylmethanol

Downstream raw materials:

2,6-dibenzhydryl-N-(2-(2,6-diethylphenylimino)acenaphthylenylidene)-4-methylbenzenamine

2,6-dibenzhydryl-N-(2-(2,6-diisopropylphenylimino)acenaphthylenylidene)-4-methylbenzenamine

2,6-dibenzhydryl-N-(2-(2,6-diethyl-4-methylphenylimino)acenaphthylenylidene)-4-methylbenzenamine

2,6-dibenzhydryl-N-(2-(2,6-dimethylphenylimino)acenaphthylenylidene)-4-methylbenzenamine