1,2,3,4,7,12-Hexahydro-11-fluoro-12-methyl-7-methylenebenz(a)anthracene

Base Information

Chemical Name:1,2,3,4,7,12-Hexahydro-11-fluoro-12-methyl-7-methylenebenz(a)anthracene
CAS No.:111771-35-8
Molecular Formula:C₂₀H₁₉F
Molecular Weight:278.369
Hs Code.:
DSSTox Substance ID:DTXSID70920564
Mol file:111771-35-8.mol

Synonyms:BRN 5079669;1,2,3,4,7,12-Hexahydro-11-fluoro-12-methyl-7-methylenebenz(a)anthracene;11-Fluoro-1,2,3,4,7,12-hexahydro-12-methyl-7-methylenebenz(a)anthracene;Benz(a)anthracene, 1,2,3,4,7,12-hexahydro-11-fluoro-12-methyl-7-methylene-;111771-35-8;DTXSID70920564;LS-27836;11-FLUORO-12-METHYL-7-METHYLIDENE-1,2,3,4,7,12-HEXAHYDROTETRAPHENE

Suppliers and Price of 1,2,3,4,7,12-Hexahydro-11-fluoro-12-methyl-7-methylenebenz(a)anthracene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 1 raw suppliers

Chemical Property of 1,2,3,4,7,12-Hexahydro-11-fluoro-12-methyl-7-methylenebenz(a)anthracene

Chemical Property:

Vapor Pressure:8.03E-06mmHg at 25°C
Boiling Point:386.2°C at 760 mmHg
Flash Point:197.6°C
Density:1.14g/cm³
XLogP3:5.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:278.147078768
Heavy Atom Count:21
Complexity:414

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1C2=C(C=CC3=C2CCCC3)C(=C)C4=C1C(=CC=C4)F

Technology Process of 1,2,3,4,7,12-Hexahydro-11-fluoro-12-methyl-7-methylenebenz(a)anthracene

There total 2 articles about 1,2,3,4,7,12-Hexahydro-11-fluoro-12-methyl-7-methylenebenz(a)anthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 111771-11-0
11-fluoro-1,2,3,4-tetrahydro-7,12-dimethylbenz anthracene

: 111771-35-8
11-fluoro-1,2,3,4,7,12-hexahydro-12-methyl-7-methylenebenz anthracene

Guidance literature:: With toluene-4-sulfonic acid; In benzene; for 1h; Heating;
DOI:10.1021/jo00237a023

Reference yield:

: 111771-34-7,111793-71-6
11-fluoro-1,2,3,4-tetrahydro-7,12-dimethylbenz anthracene-7,12-diol

: 111771-35-8
11-fluoro-1,2,3,4,7,12-hexahydro-12-methyl-7-methylenebenz anthracene

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / LiAlH₄, TiCl₃ / tetrahydrofuran / 3 h / Heating

2: 85 percent / p-TsOH / benzene / 1 h / Heating

With lithium aluminium tetrahydride; titanium(III) chloride; toluene-4-sulfonic acid; In tetrahydrofuran; benzene;
DOI:10.1021/jo00237a023