C₁₇H₁₉^(1-)*Li⁽¹⁺⁾

Base Information

• Chemical Name: C₁₇H₁₉^(1-)*Li⁽¹⁺⁾
• CAS No.: 126116-89-0
• Molecular Formula: C₁₇H₁₉*Li
• Molecular Weight: 230.279
• Mol file: 126116-89-0.mol

Synonyms:C₁₇H₁₉^(1-)*Li⁽¹⁺⁾

Chemical Property of C₁₇H₁₉^(1-)*Li⁽¹⁺⁾

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of C₁₇H₁₉^(1-)*Li⁽¹⁺⁾

There total 1 articles about C₁₇H₁₉^(1-)*Li⁽¹⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

cyclopenta-2,4-dien-1-ylidenecyclohexane (3141-04-6) + phenyllithium (591-51-5) → C17H19(1-)*Li(1+) (126116-89-0)

Guidance literature:

In diethyl ether; dibutyl ether; at -78 - 20 ℃; for 16h;

DOI:10.1021/ja0681523

Reference yield:

C17H19(1-)*Li(1+) (126116-89-0) + dimethylsilicon dichloride (75-78-5,30107-43-8) → 2Li(1+)*(CH3)2Si(C5H3C6H10C6H5)2(2-)=(CH3)2Si(C5H3C6H10C6H5Li)2

Guidance literature:

C₁₇H₁₉^(1-)*Li⁽¹⁺⁾; dimethylsilicon dichloride; In tetrahydrofuran; at 20 ℃; for 15h;

With n-butyllithium; In diethyl ether; hexane; at -78 - 20 ℃; for 16h; Further stages.;

DOI:10.1021/ja0681523

Reference yield:

C17H19(1-)*Li(1+) (126116-89-0) + dimethylsilicon dichloride (75-78-5,30107-43-8) → C36H44Si + C36H44Si

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 15h; Title compound not separated from byproducts.;

DOI:10.1021/ja0681523

upstream raw materials:

cyclopenta-2,4-dien-1-ylidenecyclohexane

phenyllithium

Refernces

• 1、 Erker, Gerhard,Aul, Rainer. "Hydroboration of Bis(alkenylcyclopentadienyl)zirconium Dichlorides". . p. 1301 - 1310. Retrieved 2007/10/02.