acetic acid 6-benzyloxymethyl-2-ethylsulfanyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester

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Chemical Name:acetic acid 6-benzyloxymethyl-2-ethylsulfanyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester
CAS No.:919078-11-8
Molecular Formula:C₂₀H₂₆Cl₃NO₆S
Molecular Weight:514.855
Hs Code.:

Synonyms:acetic acid 6-benzyloxymethyl-2-ethylsulfanyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester

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Chemical Property of acetic acid 6-benzyloxymethyl-2-ethylsulfanyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester

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Technology Process of acetic acid 6-benzyloxymethyl-2-ethylsulfanyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester

There total 2 articles about acetic acid 6-benzyloxymethyl-2-ethylsulfanyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1053554-37-2
ethyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-4-O-(trifluoromethylsulfonyl)-1-thio-β-D-glucopyranoside

: 919078-11-8
acetic acid 6-benzyloxymethyl-2-ethylsulfanyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester

Guidance literature:: With tetrabutylammonium borohydride; In tetrahydrofuran; at 20 ℃; for 6h;
DOI:10.1002/ejoc.200600515

Reference yield:

: 219518-10-2
ethyl 3-O-acetyl-6-O-benzyl-2-deoxy-<<(2,2,2-trichloroethoxy)carbonyl>amino>-1-thio-β-D-glucopyranoside

: 919078-11-8
acetic acid 6-benzyloxymethyl-2-ethylsulfanyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / CH₂Cl₂ / -15 - 0 °C

2: 2.2 g / nBu₄NBH₄ / tetrahydrofuran / 6 h / 20 °C

With pyridine; tetrabutylammonium borohydride; In tetrahydrofuran; dichloromethane;
DOI:10.1002/ejoc.200600515

Reference yield: 47.2%

: 914642-50-5
benzyl 2-acetamido-6-O-benzyl-2-deoxy-3-O-(D-1-{[2-(phenylsulfonyl)ethoxy]carbonyl}ethyl)-α-D-glucopyranoside

: 919078-11-8
acetic acid 6-benzyloxymethyl-2-ethylsulfanyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester

: 919078-14-1
2-{3-[4-acetoxy-6-benzyloxymethyl-3-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-2-yloxy]-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-tetrahydro-pyran-4-yloxy}-propionic acid 2-benzenesulfonyl-ethyl ester

Guidance literature:: With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; In dichloromethane; at -45 - 0 ℃; for 16h;
DOI:10.1002/ejoc.200600515