(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)(phenyl)}

Base Information

Chemical Name:(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)(phenyl)}
CAS No.:111237-18-4
Molecular Formula:C₃₆H₃₅FeO₄P
Molecular Weight:620.465
Hs Code.:

Synonyms:(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)(phenyl)}

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Chemical Property of (Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)(phenyl)}

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Technology Process of (Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)(phenyl)}

There total 1 articles about (Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)(phenyl)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80473-66-1
(lithium)2(CN)(phenyl)2cuprate

: 111237-31-1
{(Cp)iron(carbonyl){P(O(phenyl))3}{η2-(methyl)CCCH(methyl)2}tetrafluoroborate

: 111237-25-3
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(methyl)C(CH(methyl)2)phenyl}

: 111237-18-4
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH(methyl)2)C(methyl)phenyl}

Guidance literature:: In tetrahydrofuran; Cold (-78°C) THF is added to (CpFeCO(POPh)3)(η2-MeCCCHMe2)(BF4) (N2), mixt. treated with Me2CuCNLi2 in THF, resulting soln. is stirred for 10 min, removed from cold bath, stirred (1-2 h).; Evapn. of solvent, chromy. of residue on Al2O3 (eluant: hexane/CH2Cl2), yields yellow oil a 5:1 mixt. of regioisomers as indicated by (1)H NMR, elem. anal.;

Reference yield: 91.0%

: 111237-18-4
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH2O(methyl))C(methyl)(phenyl)}

: 111237-21-9
(Cp)iron(carbonyl){P(O(phenyl))3}{COC(CH₂O(methyl))C(methyl)(phenyl)}

Guidance literature:: With CO; In dichloromethane; Cooling (-78°C) of solns. of (CpFeCO(POPh)3)(eta.1-(E)-C(CH2OMe)C(Me)Ph and (Cp2Fe)(BF4), stirring (20 min, CO, 1 atm), addn. of (Cp2Fe)(BF4 in CH2Cl2 to alkenyliron complex by CO-pressure, stirring (45 min), removing from cold bath, stirring.; Filtering through Al2O3 , evapn., chromy. of oil on Al2O3 (eluant: hexane/CH2Cl2) yields yellow oil, elem. anal.;

Reference yield:

: 1282-37-7
ferrocenium(III) tetrafluoroborate

: 111237-25-3
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(methyl)C(CH(methyl)2)phenyl}

: 111237-18-4
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(E)-C(CH(methyl)2)C(methyl)phenyl}

: 102-54-5,55404-68-7
ferrocene

: 111237-27-5
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(Z)-COC(methyl)C(phenyl)CH(methyl)2}

: 111237-26-4
(Cp)iron(carbonyl){P(O(phenyl))3}{η1-(Z)-COC(CH(methyl)2)C(phenyl)methyl}

Guidance literature:: With CO; In dichloromethane; Cooling (-78°C) of solns. of approx. 5:1 mixt. of alkenyliron complex and (Cp2Fe)(BF4), stirring (20 min, CO, 1 atm), addn. of (Cp2Fe)(BF4) soln. to iron complex by CO-pressure, stirring (45 min), removing from cold bath, stirring (1 h).; Chromy. (Al2O3, hexane and hexane/CH2Cl2) yields first ferrocene, then a 4:1 mixt. of stereoisomers in 84 % yield, elem. anal.;