(2S,3S,3aR,8bR)-6,8-Dimethoxy-3a-(4-methoxy-phenyl)-1-oxo-3-phenyl-8b-trimethylsilanyloxy-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester

Base Information

Chemical Name:(2S,3S,3aR,8bR)-6,8-Dimethoxy-3a-(4-methoxy-phenyl)-1-oxo-3-phenyl-8b-trimethylsilanyloxy-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester
CAS No.:132491-33-9
Molecular Formula:C₃₉H₄₀O₁₀Si
Molecular Weight:696.826
Hs Code.:

(2S,3S,3aR,8bR)-6,8-Dimethoxy-3a-(4-methoxy-phenyl)-1-oxo-3-phenyl-8b-trimethylsilanyloxy-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester

Synonyms:(2S,3S,3aR,8bR)-6,8-Dimethoxy-3a-(4-methoxy-phenyl)-1-oxo-3-phenyl-8b-trimethylsilanyloxy-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester

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Chemical Property of (2S,3S,3aR,8bR)-6,8-Dimethoxy-3a-(4-methoxy-phenyl)-1-oxo-3-phenyl-8b-trimethylsilanyloxy-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester

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Technology Process of (2S,3S,3aR,8bR)-6,8-Dimethoxy-3a-(4-methoxy-phenyl)-1-oxo-3-phenyl-8b-trimethylsilanyloxy-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester

There total 7 articles about (2S,3S,3aR,8bR)-6,8-Dimethoxy-3a-(4-methoxy-phenyl)-1-oxo-3-phenyl-8b-trimethylsilanyloxy-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 500-99-2
3,5-dimethoxyphenol

: 132491-33-9
(2S,3S,3aR,8bR)-6,8-Dimethoxy-3a-(4-methoxy-phenyl)-1-oxo-3-phenyl-8b-trimethylsilanyloxy-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester

Guidance literature:: Multi-step reaction with 4 steps

2: 73 percent / DABCO, OsO₄, NMO / tetrahydrofuran; H₂O / Ambient temperature

3: C₅H₅N*SO₃, (C₂H₅)3N / dimethylsulfoxide / Ambient temperature

4: (i-C₃H₇)2NC₂H₅ / benzene / Ambient temperature

With 1,4-diaza-bicyclo[2.2.2]octane; osmium(VIII) oxide; N-methyl-2-indolinone; sulfur trioxide pyridine complex; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; water; dimethyl sulfoxide; benzene;
DOI:10.1021/ja00180a081

Reference yield:

: 65092-79-7,69979-56-2,71830-47-2,71830-48-3
3,4-Dimethyl-2-phenyl-6-[1-phenyl-meth-(Z)-ylidene]-[1,4]oxazepane-5,7-dione

: 132491-33-9
(2S,3S,3aR,8bR)-6,8-Dimethoxy-3a-(4-methoxy-phenyl)-1-oxo-3-phenyl-8b-trimethylsilanyloxy-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester

Guidance literature:: Multi-step reaction with 5 steps

3: 73 percent / DABCO, OsO₄, NMO / tetrahydrofuran; H₂O / Ambient temperature

4: C₅H₅N*SO₃, (C₂H₅)3N / dimethylsulfoxide / Ambient temperature

5: (i-C₃H₇)2NC₂H₅ / benzene / Ambient temperature

With 1,4-diaza-bicyclo[2.2.2]octane; osmium(VIII) oxide; N-methyl-2-indolinone; sulfur trioxide pyridine complex; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; water; dimethyl sulfoxide; benzene;
DOI:10.1021/ja00180a081

Reference yield:

: 132463-98-0
(1S,2S,3S,3aR,8bS)-1,8b-Dihydroxy-6,8-dimethoxy-3a-(4-methoxy-phenyl)-3-phenyl-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester

: 132491-33-9
(2S,3S,3aR,8bR)-6,8-Dimethoxy-3a-(4-methoxy-phenyl)-1-oxo-3-phenyl-8b-trimethylsilanyloxy-1,3,3a,8b-tetrahydro-benzo[b]cyclopenta[d]furan-2,2-dicarboxylic acid benzyl ester methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: C₅H₅N*SO₃, (C₂H₅)3N / dimethylsulfoxide / Ambient temperature

2: (i-C₃H₇)2NC₂H₅ / benzene / Ambient temperature

With sulfur trioxide pyridine complex; triethylamine; N-ethyl-N,N-diisopropylamine; In dimethyl sulfoxide; benzene;
DOI:10.1021/ja00180a081