C₂₄H₂₆O₆

Base Information

• Chemical Name: C₂₄H₂₆O₆
• CAS No.: 211692-12-5
• Molecular Formula: C₂₄H₂₆O₆
• Molecular Weight: 410.467
• Mol file: 211692-12-5.mol

Synonyms:C₂₄H₂₆O₆

Chemical Property of C₂₄H₂₆O₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₄H₂₆O₆

There total 12 articles about C₂₄H₂₆O₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-(2R,5R,6S)-6-Benzyloxy-3,13,20-trioxa-tricyclo[13.2.2.12,5]icosa-1(18),8,15(19),16-tetraen-14-one (211692-00-1) → C24H26O6 (211692-12-5) + C24H26O6

Guidance literature:

With disodium hydrogenphosphate; sodium dihydrogenphosphate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 20 ℃; for 3h;

DOI:10.1002/(SICI)1521-3773(19980619)37:11<1566::AID-ANIE1566>3.0.CO;2-U

Reference yield:

(S)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-ol (79364-35-5) → C24H26O6 (211692-12-5)

Guidance literature:

Multi-step reaction with 11 steps

1: NaH, imidazole / dimethylformamide

2: 1.) O₃, 2.) PPH₃ / 1.) CH₂Cl₂, 2.) CH₂Cl₂

3: tetrahydrofuran / 0 °C

4: 79 percent / EtCO₂H / toluene / Heating

5: LiAlH₄ / tetrahydrofuran / 0 °C

6: Et₃N / CH₂Cl₂

7: AcOH, H₂O

8: TsOH, molecular sieves 4 Angstroem

9: H₂O, LiOH / methanol; tetrahydrofuran

10: 1.) 2,4,6-trichlorobenzoyl chloride, Et₃N, 2.) DMAP / 1.) THF, 2 h, 2.) THF, toluene, reflux, 20 h

11: MCPBA, NaH₂PO₄, Na₂HPO₄ / CH₂Cl₂ / 3 h / 0 - 20 °C

With 1H-imidazole; dmap; lithium hydroxide; disodium hydrogenphosphate; sodium dihydrogenphosphate; lithium aluminium tetrahydride; 4 A molecular sieve; 2,4,6-trichlorobenzoyl chloride; water; sodium hydride; toluene-4-sulfonic acid; ozone; acetic acid; propionic acid; triethylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; toluene;

DOI:10.1002/(SICI)1521-3773(19980619)37:11<1566::AID-ANIE1566>3.0.CO;2-U

Reference yield:

(3S,4R)-3-O-benzyl-4,5-O-isopropylidene-3,4,5-trihydroxypentanal (103795-36-4) → C24H26O6 (211692-12-5)

Guidance literature:

Multi-step reaction with 9 steps

1: tetrahydrofuran / 0 °C

2: 79 percent / EtCO₂H / toluene / Heating

3: LiAlH₄ / tetrahydrofuran / 0 °C

4: Et₃N / CH₂Cl₂

5: AcOH, H₂O

6: TsOH, molecular sieves 4 Angstroem

7: H₂O, LiOH / methanol; tetrahydrofuran

8: 1.) 2,4,6-trichlorobenzoyl chloride, Et₃N, 2.) DMAP / 1.) THF, 2 h, 2.) THF, toluene, reflux, 20 h

9: MCPBA, NaH₂PO₄, Na₂HPO₄ / CH₂Cl₂ / 3 h / 0 - 20 °C

With dmap; lithium hydroxide; disodium hydrogenphosphate; sodium dihydrogenphosphate; lithium aluminium tetrahydride; 4 A molecular sieve; 2,4,6-trichlorobenzoyl chloride; water; toluene-4-sulfonic acid; acetic acid; propionic acid; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane; toluene;

DOI:10.1002/(SICI)1521-3773(19980619)37:11<1566::AID-ANIE1566>3.0.CO;2-U

upstream raw materials:

(E)-(2R,5R,6S)-6-Benzyloxy-3,13,20-trioxa-tricyclo[13.2.2.1^2,5]icosa-1⁽¹⁸⁾,8,15⁽¹⁹⁾,16-tetraen-14-one

(S)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-ol

(3S,4R)-3-O-benzyl-4,5-O-isopropylidene-3,4,5-trihydroxypentanal

(R)-4-((S)-1-(benzyloxy)but-3-ene-1-yl)-2,2-dimethyl-1,3-dioxypentane