Technology Process of C37H51BF2N2OSi2
There total 5 articles about C37H51BF2N2OSi2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 0.08 h / 20 °C
2: boron trifluoride diethyl etherate; triethylamine / 1.5 h / 20 °C
3: N-iodo-succinimide / dichloromethane; N,N-dimethyl-formamide / 24 h / 20 °C
4: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; diisopropylamine / 2 h / 90 °C
With
bis-triphenylphosphine-palladium(II) chloride; N-iodo-succinimide; copper(l) iodide; boron trifluoride diethyl etherate; triethylamine; diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane; N,N-dimethyl-formamide; toluene;
4: Sonogashira coupling;
DOI:10.1021/ma200839q
- Guidance literature:
-
Multi-step reaction with 3 steps
1: boron trifluoride diethyl etherate; triethylamine / 1.5 h / 20 °C
2: N-iodo-succinimide / dichloromethane; N,N-dimethyl-formamide / 24 h / 20 °C
3: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; diisopropylamine / 2 h / 90 °C
With
bis-triphenylphosphine-palladium(II) chloride; N-iodo-succinimide; copper(l) iodide; boron trifluoride diethyl etherate; triethylamine; diisopropylamine;
In
dichloromethane; N,N-dimethyl-formamide;
3: Sonogashira coupling;
DOI:10.1021/ma200839q
- Guidance literature:
-
Multi-step reaction with 5 steps
1: trifluoroacetic acid / dichloromethane / 1.5 h / 20 °C
2: 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 0.08 h / 20 °C
3: boron trifluoride diethyl etherate; triethylamine / 1.5 h / 20 °C
4: N-iodo-succinimide / dichloromethane; N,N-dimethyl-formamide / 24 h / 20 °C
5: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; diisopropylamine / 2 h / 90 °C
With
bis-triphenylphosphine-palladium(II) chloride; N-iodo-succinimide; copper(l) iodide; boron trifluoride diethyl etherate; triethylamine; diisopropylamine; trifluoroacetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
dichloromethane; N,N-dimethyl-formamide; toluene;
5: Sonogashira coupling;
DOI:10.1021/ma200839q