tris(diphenylacetylene)tungsten monocarbonyl

Base Information

Chemical Name:tris(diphenylacetylene)tungsten monocarbonyl
CAS No.:12120-72-8
Molecular Formula:C₄₃H₃₀OW
Molecular Weight:746.561
Hs Code.:

Synonyms:tris(diphenylacetylene)tungsten monocarbonyl

Suppliers and Price of tris(diphenylacetylene)tungsten monocarbonyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tris(diphenylacetylene)tungsten monocarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tris(diphenylacetylene)tungsten monocarbonyl

There total 2 articles about tris(diphenylacetylene)tungsten monocarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 205106-38-3
(1,3,5-trimethyl-1,3,5-triazacyclohexane)tungsten⁽⁰⁾ tricarbonyl

: 501-65-5
diphenyl acetylene

: 12120-72-8
tris(diphenylacetylene)tungsten monocarbonyl

Guidance literature:: In acetone; N2-atmosphere; refluxing W-complex with excess of alkyne for 2 h; addn. of Al2O3, solvent removal (vac.), extn. into C6H6 at room temp., evapn., recrystn. (C6H6/EtOH);
DOI:10.1016/S0022-328X(98)00642-1

Reference yield: 80.0%

: 16800-47-8,30958-95-3
tricarbonyl-tris(acetonitrile)tungsten⁽⁰⁾

: 501-65-5
diphenyl acetylene

: 12120-72-8
tris(diphenylacetylene)tungsten monocarbonyl

Guidance literature:: In ethanol; N2-atmosphere; refluxing (20 h); crystn.; elem. anal.;
DOI:10.1016/S0020-1693(00)95000-X

Reference yield: 84.0%

: (η(5)-cyclopentadienyl)W(CO)2(C(CH3))

: 12120-72-8
tris(diphenylacetylene)tungsten monocarbonyl

: {W2(μ-PhC2Ph)(CO)4(η-C5MePh4)(η-C5H5)}

Guidance literature:: In octane; a mixt. of 1 equiv of (W(CO)(PhC2Ph)3) and 1.25 equiv of (W(CMe)(CO)2(C5H5)) in octane was refluxed for 1 h; solvent removed in vac., the residue extd. with light petroleum, the extracts chromd., eluted with light petroleum-Et2O, solvent removed in vac.; elem. anal.;
DOI:10.1039/DT9850000905