methyl (2R,3R,4S)-5-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanoate

Base Information

Chemical Name:methyl (2R,3R,4S)-5-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanoate
CAS No.:1096707-27-5
Molecular Formula:C₃₂H₄₂O₅Si
Molecular Weight:534.768
Hs Code.:

Synonyms:methyl (2R,3R,4S)-5-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanoate

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Chemical Property of methyl (2R,3R,4S)-5-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanoate

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Technology Process of methyl (2R,3R,4S)-5-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanoate

There total 1 articles about methyl (2R,3R,4S)-5-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 89238-99-3
O-(4-methoxybenzyl)-trichloroacetimidate

: 367264-63-9
(2R,3R,4S)-5-(tert-butyl-diphenyl-silanyloxy)-3-hydroxy-2,4-dimethyl-pentanoic acid methyl ester

: 1096707-27-5
methyl (2R,3R,4S)-5-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanoate

Guidance literature:: With trifluorormethanesulfonic acid; In diethyl ether; at 0 ℃; for 20h; Inert atmosphere;
DOI:10.1021/jo8021583

Reference yield: 94.0%

: 1096707-27-5
methyl (2R,3R,4S)-5-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanoate

: 1096707-28-6
(2S,3S,4S)-5-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentan-1-ol

Guidance literature:: methyl (2R,3R,4S)-5-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethylpentanoate; With diisobutylaluminium hydride; In hexane; dichloromethane; at 20 ℃; Inert atmosphere;

With Rochelle's salt; In hexane; dichloromethane; water; for 2h;
DOI:10.1021/jo8021583