[(2R,3S,4S,5E,9S)-3,4-dihydroxy-10-oxo-2-propyl-2,3,4,7,8,9-hexahydrooxecin-9-yl] (2E,4E)-hexa-2,4-dienoate

Base Information

• Chemical Name: [(2R,3S,4S,5E,9S)-3,4-dihydroxy-10-oxo-2-propyl-2,3,4,7,8,9-hexahydrooxecin-9-yl] (2E,4E)-hexa-2,4-dienoate
• CAS No.: 152985-39-2
• Molecular Formula: C₁₈H₂₆O₆
• Molecular Weight: 338.401
• ChEMBL ID: CHEMBL504236
• Wikidata: Q105266907
• Mol file: 152985-39-2.mol

Synonyms:CHEMBL504236

Chemical Property of [(2R,3S,4S,5E,9S)-3,4-dihydroxy-10-oxo-2-propyl-2,3,4,7,8,9-hexahydrooxecin-9-yl] (2E,4E)-hexa-2,4-dienoate

Chemical Property:

• Vapor Pressure: 1.35E-12mmHg at 25°C
• Boiling Point: 511.4°Cat760mmHg
• Flash Point: 178.8°C
• PSA: 93.06000
• Density: 1.16g/cm³
• LogP: 1.81420
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 338.17293854
• Heavy Atom Count: 24
• Complexity: 494

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC1C(C(C=CCCC(C(=O)O1)OC(=O)C=CC=CC)O)O
• Isomeric SMILES: CCC[C@@H]1[C@H]([C@H](/C=C/CC[C@@H](C(=O)O1)OC(=O)/C=C/C=C/C)O)O

Technology Process of [(2R,3S,4S,5E,9S)-3,4-dihydroxy-10-oxo-2-propyl-2,3,4,7,8,9-hexahydrooxecin-9-yl] (2E,4E)-hexa-2,4-dienoate

There total 15 articles about [(2R,3S,4S,5E,9S)-3,4-dihydroxy-10-oxo-2-propyl-2,3,4,7,8,9-hexahydrooxecin-9-yl] (2E,4E)-hexa-2,4-dienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

hexa-2,4-dienoic acid 2,2-dimethyl-6-oxo-4-propyl-3a,6,7,8,9,11a-hexahydro-4H-1,3,5-trioxa-cyclopentacyclodecen-7-yl ester (443309-11-3) → (-)-pinolidoxin (152985-39-2)

Guidance literature:

With hydrogenchloride; In methanol; at 65 ℃;

DOI:10.1021/ja020238i

Reference yield: 95.0%

(2E,4E)-Hexa-2,4-dienoic acid (E)-(3aS,4S,11aR)-2,2-dimethyl-6-oxo-4-propyl-3a,6,7,8,9,11a-hexahydro-4H-1,3,5-trioxa-cyclopentacyclodecen-7-yl ester → (-)-pinolidoxin (152985-39-2)

Guidance literature:

With hydrogenchloride; In methanol; at 65 ℃; for 1.25h;

DOI:10.1021/ja020238i

Reference yield: 81.0%

(2E,4E)-Hexa-2,4-dienoic acid (E)-(3aR,4R,7S,11aS)-2,2-dimethyl-6-oxo-4-propyl-3a,6,7,8,9,11a-hexahydro-4H-1,3,5-trioxa-cyclopentacyclodecen-7-yl ester (245420-84-2) → pinolidoxin (152985-39-2)

Guidance literature:

With ethandithiol; boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1021/jo051353p

upstream raw materials:

hexa-2,4-dienoic acid 2,2-dimethyl-6-oxo-4-propyl-3a,6,7,8,9,11a-hexahydro-4H-1,3,5-trioxa-cyclopentacyclodecen-7-yl ester

(2E,4E)-Hexa-2,4-dienoic acid (R)-1-((1S,2R,3R)-2,3-dihydroxy-1-propyl-pent-4-enyloxycarbonyl)-pent-4-enyl ester

sorbic Acid

(S)-1-((4S,5R)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)butan-1-ol

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