allyl [2,3-di-O-benzoyl-4-O-(3-fluoro-1,1,3,3-tetraisopropyl-1,3-disiloxane-1-yl)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranoside

Base Information

Chemical Name:allyl [2,3-di-O-benzoyl-4-O-(3-fluoro-1,1,3,3-tetraisopropyl-1,3-disiloxane-1-yl)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranoside
CAS No.:195316-95-1
Molecular Formula:C₆₂H₇₃FO₁₇Si₂
Molecular Weight:1165.42
Hs Code.:

Synonyms:allyl [2,3-di-O-benzoyl-4-O-(3-fluoro-1,1,3,3-tetraisopropyl-1,3-disiloxane-1-yl)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranoside

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Chemical Property of allyl [2,3-di-O-benzoyl-4-O-(3-fluoro-1,1,3,3-tetraisopropyl-1,3-disiloxane-1-yl)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranoside

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Technology Process of allyl [2,3-di-O-benzoyl-4-O-(3-fluoro-1,1,3,3-tetraisopropyl-1,3-disiloxane-1-yl)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranoside

There total 6 articles about allyl [2,3-di-O-benzoyl-4-O-(3-fluoro-1,1,3,3-tetraisopropyl-1,3-disiloxane-1-yl)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 195316-94-0
allyl [2,3-di-O-benzoyl-4,6-O-(1,1,3,3-tetraisopropyl-1,3-disiloxane-1,3-diyl)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranoside

: 195316-95-1
allyl [2,3-di-O-benzoyl-4-O-(3-fluoro-1,1,3,3-tetraisopropyl-1,3-disiloxane-1-yl)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranoside

Guidance literature:: With pyridine polyhydrogen fluoride; In dichloromethane; for 0.166667h; Ambient temperature;
DOI:10.1080/07328309708006537

Reference yield:

: 258854-17-0
1-O-Allyl 6-O-trityl-α-D-galactopyranoside

: 195316-95-1
allyl [2,3-di-O-benzoyl-4-O-(3-fluoro-1,1,3,3-tetraisopropyl-1,3-disiloxane-1-yl)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 2 h / Ambient temperature

2: aq. AcOH / 6 h / 85 °C

3: 95 percent / TFA / 1 h / Ambient temperature

4: 81 percent / BF₃*OEt₂, Et₃N / CH₂Cl₂ / 0.5 h

5: 84 percent / pyridine polyhydrogen fluoride / CH₂Cl₂ / 0.17 h / Ambient temperature

With pyridine polyhydrogen fluoride; boron trifluoride diethyl etherate; acetic acid; triethylamine; trifluoroacetic acid; In dichloromethane;
DOI:10.1080/07328309708006537

Reference yield:

: 195316-89-3
allyl 2,3,4-tri-O-benzoyl-α-D-galactopyranoside

: 195316-95-1
allyl [2,3-di-O-benzoyl-4-O-(3-fluoro-1,1,3,3-tetraisopropyl-1,3-disiloxane-1-yl)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / TFA / 1 h / Ambient temperature

2: 81 percent / BF₃*OEt₂, Et₃N / CH₂Cl₂ / 0.5 h

3: 84 percent / pyridine polyhydrogen fluoride / CH₂Cl₂ / 0.17 h / Ambient temperature

With pyridine polyhydrogen fluoride; boron trifluoride diethyl etherate; triethylamine; trifluoroacetic acid; In dichloromethane;
DOI:10.1080/07328309708006537