dicarbonyl(cyclopentadienyl)phenylthiomanganese

Base Information

• Chemical Name: dicarbonyl(cyclopentadienyl)phenylthiomanganese
• CAS No.: 114095-82-8
• Molecular Formula: C₁₃H₁₀MnO₂S
• Molecular Weight: 285.225
• Mol file: 114095-82-8.mol

Synonyms:dicarbonyl(cyclopentadienyl)phenylthiomanganese

Chemical Property of dicarbonyl(cyclopentadienyl)phenylthiomanganese

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of dicarbonyl(cyclopentadienyl)phenylthiomanganese

There total 4 articles about dicarbonyl(cyclopentadienyl)phenylthiomanganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

dicarbonyl(cyclopentadienyl)(diethylsulfide)manganese (40674-64-4) + dicarbonyl(cyclopentadienyl)(S-phenyl diphenylphosphinothioite)manganese (266692-52-8) → dicarbonyl(cyclopentadienyl)phenylthiomanganese (114095-82-8)

Guidance literature:

In octane; 90°C, 30 min; cooling, solvent evapn. in vacuum, residue recrystn. (hexane, -80°C);

Reference yield: 79.0%

dicarbonyl(cyclopentadienyl)(diethylamino)manganese + dicarbonyl(cyclopentadienyl)(S-phenyl diphenylphosphinothioite)manganese (266692-52-8) → dicarbonyl(cyclopentadienyl)phenylthiomanganese (114095-82-8)

Guidance literature:

In octane; 90°C, 30 min; cooling, solvent evapn. in vacuum, residue recrystn. (hexane, -80°C);

Reference yield: 50.0%

cymantrene (12079-65-1) + triphenyl thiophosphite (1095-04-1) → C5H5Mn(CO)2(P(SC6H5)3) + dicarbonyl(cyclopentadienyl)phenylthiomanganese (114095-82-8)

Guidance literature:

With C₄H₈O; In tetrahydrofuran; Irradiation (UV/VIS); cymantrene in THF is irradiated under Ar for 2 h at -5°C, to the soln. of CpMn(CO)2(THF) is added the thiophosphite, the soln. is slowly warmed up to 20°C, exposed for 12-14 h at this temp. without irradiation; removal of THF in vac., the residue is chromd., recrystd. (hexane, -80,degree.C);

DOI:10.1007/BF00698463

upstream raw materials:

cymantrene

triphenyl thiophosphite

dicarbonyl(cyclopentadienyl)(diethylsulfide)manganese

dicarbonyl(cyclopentadienyl)(S-phenyl diphenylphosphinothioite)manganese

Downstream raw materials:

cymantrene

((C₅H₅)(CO)2Mn)2S(C₆H₅)⁽¹⁺⁾*PF₆^(1-)=((C₅H₅)(CO)2Mn)2S(C₆H₅)(PF₆)