(SP-4-2)-[Pt{κC¹,κSe⁹-(9-triptycyl)Se(2-)}{P(OPh)₃}₂]

Base Information

• Chemical Name: (SP-4-2)-[Pt{κC¹,κSe⁹-(9-triptycyl)Se(2-)}{P(OPh)₃}₂]
• CAS No.: 1443116-63-9
• Molecular Formula: C₅₆H₄₂O₆P₂PtSe
• Molecular Weight: 1146.93
• Mol file: 1443116-63-9.mol

Synonyms:(SP-4-2)-[Pt{κC¹,κSe⁹-(9-triptycyl)Se(2-)}{P(OPh)₃}₂]

Chemical Property of (SP-4-2)-[Pt{κC¹,κSe⁹-(9-triptycyl)Se(2-)}{P(OPh)₃}₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (SP-4-2)-[Pt{κC¹,κSe⁹-(9-triptycyl)Se(2-)}{P(OPh)₃}₂]

There total 11 articles about (SP-4-2)-[Pt{κC¹,κSe⁹-(9-triptycyl)Se(2-)}{P(OPh)₃}₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

cis-[PtH(Se(9-triptycyl)){P(OPh)3}2] (1443116-62-8) + phenylacetylene (536-74-3) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + (SP-4-2)-[Pt{κC1,κSe9-(9-triptycyl)Se(2-)}{P(OPh)3}2] (1443116-63-9)

Guidance literature:

In toluene; at 20 - 110 ℃; for 15h; Inert atmosphere;

DOI:10.1246/bcsj.20130295

Reference yield: 16.0%

cis-[PtH(Se(9-triptycyl)){P(OPh)3}2] (1443116-62-8) + phenylacetylene (536-74-3) → (SP-4-2)-[Pt{κC,κP-(Z)-CH=C(Ph)OP(OPh)2}(Se(9-triptycyl))-{P(OPh)3}] (1579984-49-8) + (SP-4-2)-[Pt{κC1,κSe9-(9-triptycyl)Se(2-)}{P(OPh)3}2] (1443116-63-9)

Guidance literature:

With triphenyl phosphite; In toluene; at 110 ℃; for 15h; Inert atmosphere;

DOI:10.1246/bcsj.20130295

Reference yield:

cis-[PtH(Se(9-triptycyl)){P(OPh)3}2] (1443116-62-8) → (SP-4-2)-[Pt{κC1,κSe9-(9-triptycyl)Se(2-)}{P(OPh)3}2] (1443116-63-9)

Guidance literature:

In 5,5-dimethyl-1,3-cyclohexadiene; at 130 ℃; for 17h;

DOI:10.1246/bcsj.20130295

upstream raw materials:

dichloro-bis(triphenylphosphite)-platinum(II)

triphenyl phosphite

phenylacetylene

cis-[PtH(Se(9-triptycyl)){P(OPh)₃}₂]