(Z)-2-(5-(benzo[c]phenanthren-2-yl)oct-4-en-4-yl)-5-phenyl-5Hbenzo[b]phosphindole 5-oxide

Base Information

Chemical Name:(Z)-2-(5-(benzo[c]phenanthren-2-yl)oct-4-en-4-yl)-5-phenyl-5Hbenzo[b]phosphindole 5-oxide
CAS No.:1449060-54-1
Molecular Formula:C₄₄H₃₇OP
Molecular Weight:612.751
Hs Code.:

Synonyms:(Z)-2-(5-(benzo[c]phenanthren-2-yl)oct-4-en-4-yl)-5-phenyl-5Hbenzo[b]phosphindole 5-oxide

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Chemical Property of (Z)-2-(5-(benzo[c]phenanthren-2-yl)oct-4-en-4-yl)-5-phenyl-5Hbenzo[b]phosphindole 5-oxide

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Technology Process of (Z)-2-(5-(benzo[c]phenanthren-2-yl)oct-4-en-4-yl)-5-phenyl-5Hbenzo[b]phosphindole 5-oxide

There total 8 articles about (Z)-2-(5-(benzo[c]phenanthren-2-yl)oct-4-en-4-yl)-5-phenyl-5Hbenzo[b]phosphindole 5-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1393367-71-9
(E)-2-(5-(benzo[c]phenanthren-2-yl)oct-4-en-4-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1449060-51-8
5-oxido-5-phenyl-5H-benzo[b]phosphindol-2-yl trifluoromethanesulfonate

: 1449060-54-1
(Z)-2-(5-(benzo[c]phenanthren-2-yl)oct-4-en-4-yl)-5-phenyl-5Hbenzo[b]phosphindole 5-oxide

Guidance literature:: With PdCl₂(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl)2; caesium carbonate; In tetrahydrofuran; water; at 85 ℃; for 6h; Inert atmosphere;
DOI:10.1002/chem.201300844

Reference yield:

: 202865-84-7
4-bromo-3-iodo-phenol

: 1449060-54-1
(Z)-2-(5-(benzo[c]phenanthren-2-yl)oct-4-en-4-yl)-5-phenyl-5Hbenzo[b]phosphindole 5-oxide

Guidance literature:: Multi-step reaction with 7 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 4 h / 20 °C / Inert atmosphere

2.1: sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene; water; ethanol / 6 h / 85 °C / Inert atmosphere

3.1: tert.-butyl lithium / diethyl ether; pentane / 1 h / -78 °C / Inert atmosphere

3.2: 20 °C / Inert atmosphere

4.1: dihydrogen peroxide / water; dichloromethane / 0.17 h / Inert atmosphere

5.1: tetrabutyl ammonium fluoride / tetrahydrofuran; water; dichloromethane / 0.5 h / Inert atmosphere

6.1: caesium carbonate / N,N-dimethyl-formamide / 18 h / 20 °C / Inert atmosphere

7.1: caesium carbonate; PdCl₂(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl)2 / tetrahydrofuran; water / 6 h / 85 °C / Inert atmosphere

With 1H-imidazole; tetrakis(triphenylphosphine) palladium⁽⁰⁾; PdCl₂(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl)2; tetrabutyl ammonium fluoride; dihydrogen peroxide; tert.-butyl lithium; sodium carbonate; caesium carbonate; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; pentane; 2.1: |Suzuki Coupling / 7.1: |Suzuki Coupling;
DOI:10.1002/chem.201300844

Reference yield:

: 1449060-48-3
2-hydroxy-5-phenyl-5H-benzo[b]phosphindole 5-oxide

: 1449060-54-1
(Z)-2-(5-(benzo[c]phenanthren-2-yl)oct-4-en-4-yl)-5-phenyl-5Hbenzo[b]phosphindole 5-oxide

Guidance literature:: Multi-step reaction with 2 steps

1: caesium carbonate / N,N-dimethyl-formamide / 18 h / 20 °C / Inert atmosphere

2: caesium carbonate; PdCl₂(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl)2 / tetrahydrofuran; water / 6 h / 85 °C / Inert atmosphere

With PdCl₂(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl)2; caesium carbonate; In tetrahydrofuran; water; N,N-dimethyl-formamide; 2: |Suzuki Coupling;
DOI:10.1002/chem.201300844