(3aR,5R,6R,6aR)-2,2-Dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

Base Information

Chemical Name:(3aR,5R,6R,6aR)-2,2-Dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol
CAS No.:700870-84-4
Molecular Formula:C₁₅H₂₀O₄
Molecular Weight:264.321
Hs Code.:

Synonyms:(3aR,5R,6R,6aR)-2,2-Dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

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Chemical Property of (3aR,5R,6R,6aR)-2,2-Dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

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Technology Process of (3aR,5R,6R,6aR)-2,2-Dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

There total 3 articles about (3aR,5R,6R,6aR)-2,2-Dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 700870-82-2
(3aR,5R,6aS)-2,2-Dimethyl-5-phenethyl-dihydro-furo[2,3-d][1,3]dioxol-6-one

: 700870-84-4
(3aR,5R,6R,6aR)-2,2-Dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

Guidance literature:: With sodium tetrahydroborate; In methanol; at 20 ℃; for 12h;
DOI:10.1021/jo049858n

Reference yield:

: (3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxole

: 700870-84-4
(3aR,5R,6R,6aR)-2,2-Dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / hydrogen / Pd/C / tetrahydrofuran / 12 h / 20 °C

2: 93 percent / oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / -78 - 0 °C

3: 440 mg / NaBH₄ / methanol / 12 h / 20 °C

With sodium tetrahydroborate; oxalyl dichloride; hydrogen; dimethyl sulfoxide; triethylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; 2: Swern oxidation;
DOI:10.1021/jo049858n

Reference yield:

: 137585-73-0
5,6-dideoxy-1,2-O-(isopropylidene)-6-phenyl-α-D-xylo-hexofuranose

: 700870-84-4
(3aR,5R,6R,6aR)-2,2-Dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / -78 - 0 °C

2: 440 mg / NaBH₄ / methanol / 12 h / 20 °C

With sodium tetrahydroborate; oxalyl dichloride; dimethyl sulfoxide; triethylamine; In methanol; dichloromethane; 1: Swern oxidation;
DOI:10.1021/jo049858n