benzyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranosyl-(1→2)-2,3-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside

Base Information

• Chemical Name: benzyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranosyl-(1→2)-2,3-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside
• CAS No.: 1428344-43-7
• Molecular Formula: C₁₁₂H₁₀₂F₁₀O₂₁
• Molecular Weight: 1974.01
• Mol file: 1428344-43-7.mol

Synonyms:benzyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranosyl-(1→2)-2,3-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside

Chemical Property of benzyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranosyl-(1→2)-2,3-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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Useful:

Technology Process of benzyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranosyl-(1→2)-2,3-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside

There total 1 articles about benzyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranosyl-(1→2)-2,3-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

pent-4-enyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-Obenzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside (1428344-40-4) + benzyl 3,4-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside (1428344-42-6) → benzyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranosyl-(1→2)-2,3-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside (1428344-43-7)

Guidance literature:

pent-4-enyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-Obenzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside; benzyl 3,4-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside; In toluene; for 2h;

With N-iodo-succinimide; triethylsilyl trifluoromethyl sulfonate; In diethyl ether; toluene; at -20 ℃;

DOI:10.1021/ol400430p

Reference yield: 76.0%

benzyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranosyl-(1→2)-2,3-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside (1428344-43-7) → benzyl 3,4-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranosyl-(1→2)-2,3-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside (1428344-44-8)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In methanol; dichloromethane; water; at 20 ℃;

DOI:10.1021/ol400430p

upstream raw materials:

pent-4-enyl 3,4-di-O-benzyl-2-O-(2-naphthylmethyl)-α-L-rhamnopyranosyl-(1→4)-2,3-di-Obenzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside

benzyl 3,4-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside

Downstream raw materials:

benzyl 3,4-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranosyl-(1→2)-2,3-di-O-benzyl-α-L-rhamnopyranosyl-(1→4)-2,3-di-O-benzyl-6-O-pentafluorobenzoyl-α-D-galactopyranoside