phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside

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Chemical Name:phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside
CAS No.:1037510-10-3
Molecular Formula:C₃₆H₃₁F₃O₅S
Molecular Weight:632.7
Hs Code.:

Synonyms:phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside

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Chemical Property of phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside

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Technology Process of phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside

There total 1 articles about phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 158716-07-5
phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside

: 173019-83-5
1-(3-bromoprop-1-yn-1-yl)-4-(trifluoromethyl)benzene

: 1037510-10-3
phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 1h;
DOI:10.1021/jo7023398

Reference yield: 82.0%

: 1037510-10-3
phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside

: 1268373-47-2
C₂₃H₄₁NO₄

: 1268373-54-1
C₅₃H₆₆F₃NO₉

Guidance literature:: phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside; With 1-benzenesulfinyl piperidine; trifluoromethylsulfonic anhydride; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; at -60 ℃; for 0.5h; Inert atmosphere; Molecular sieve;

C₂₃H₄₁NO₄; In dichloromethane; at -60 ℃; for 21h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.201006230

Reference yield: 72.0%

: 1037510-10-3
phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside

: 768-95-6
1-adamanthanol

: phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-D-mannose

: 1039169-32-8
1-adamantanyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-β-D-mannopyranoside

Guidance literature:: phenyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-1-thio-α-D-mannopyranoside; With trifluoromethylsulfonic anhydride; sulfobromophthalein sodium; 4 A molecular sieve; In dichloromethane; at -70 ℃; for 0.5h;

1-adamanthanol; In dichloromethane; at -70 ℃; for 0.5h; Further stages.;
DOI:10.1021/jo7023398