1-cyclohexenylmethyl DL-4-oxo-2-cyclopentenyl ether

Base Information

• Chemical Name: 1-cyclohexenylmethyl DL-4-oxo-2-cyclopentenyl ether
• CAS No.: 109002-06-4
• Molecular Formula: C₁₂H₁₆O₂
• Molecular Weight: 192.258
• Mol file: 109002-06-4.mol

Synonyms:1-cyclohexenylmethyl DL-4-oxo-2-cyclopentenyl ether

Chemical Property of 1-cyclohexenylmethyl DL-4-oxo-2-cyclopentenyl ether

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1-cyclohexenylmethyl DL-4-oxo-2-cyclopentenyl ether

There total 8 articles about 1-cyclohexenylmethyl DL-4-oxo-2-cyclopentenyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

1-cyclohexenylmethyl DL-cis-4-hydroxy-2-cyclopentenyl ether → 1-cyclohexenylmethyl DL-4-oxo-2-cyclopentenyl ether (109002-06-4)

Guidance literature:

With sodium acetate; pyridinium chlorochromate; In dichloromethane; for 3h; Ambient temperature;

Reference yield:

1-cyclohexene-1-methanol (4845-04-9) + 4-bromocyclopent-2-enone (765-56-0,532427-10-4) → 1-cyclohexenylmethyl DL-4-oxo-2-cyclopentenyl ether (109002-06-4)

Guidance literature:

With silver carbonate; In benzene; at 40 ℃; for 18h; Yield given;

Reference yield:

cis-4-cyclopentene-1,3-diol (29783-26-4) → 1-cyclohexenylmethyl DL-4-oxo-2-cyclopentenyl ether (109002-06-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) NaH / 1.) THF, 15 min, 2.) HMPT, reflux, 4 h; room temp., overnight

2: 76 percent / pyridinium chlorochromate, NaOAc / CH₂Cl₂ / 3 h / Ambient temperature

With sodium acetate; sodium hydride; pyridinium chlorochromate; In dichloromethane;

upstream raw materials:

1-cyclohexene-1-methanol

4-bromocyclopent-2-enone

cis-4-cyclopentene-1,3-diol

4-acetoxy-cyclopentenone