1,1-(ethylenedithio)-4-<2-(methoxymethoxy)ethyl>-4-(3,4-dimethoxyphenyl)cyclohex-2-ene

Base Information

Chemical Name:1,1-(ethylenedithio)-4-<2-(methoxymethoxy)ethyl>-4-(3,4-dimethoxyphenyl)cyclohex-2-ene
CAS No.:110417-14-6
Molecular Formula:C₂₀H₂₈O₄S₂
Molecular Weight:396.572
Hs Code.:

Synonyms:1,1-(ethylenedithio)-4-<2-(methoxymethoxy)ethyl>-4-(3,4-dimethoxyphenyl)cyclohex-2-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,1-(ethylenedithio)-4-<2-(methoxymethoxy)ethyl>-4-(3,4-dimethoxyphenyl)cyclohex-2-ene

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Technology Process of 1,1-(ethylenedithio)-4-<2-(methoxymethoxy)ethyl>-4-(3,4-dimethoxyphenyl)cyclohex-2-ene

There total 9 articles about 1,1-(ethylenedithio)-4-<2-(methoxymethoxy)ethyl>-4-(3,4-dimethoxyphenyl)cyclohex-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.7%

: 107-30-2
chloromethyl methyl ether

: 110417-13-5
1,1-(ethylenedithio)-4-(3,4-dimethoxyphenyl)-4-(2-hydroxyethyl)cyclohex-2-ene

: 110417-14-6
1,1-(ethylenedithio)-4-<2-(methoxymethoxy)ethyl>-4-(3,4-dimethoxyphenyl)cyclohex-2-ene

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; Ambient temperature;
DOI:10.1021/jo00232a032

Reference yield:

: 79214-95-2
4-(cyanomethyl)-4-(3,4-dimethoxyphenyl)cyclohex-2-en-1-one

: 110417-14-6
1,1-(ethylenedithio)-4-<2-(methoxymethoxy)ethyl>-4-(3,4-dimethoxyphenyl)cyclohex-2-ene

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / boron trifluoride etherate / CH₂Cl₂ / 2 h / 0 °C

2: 94.5 percent / diisobutylaluminum hydride / toluene / 1 h / -78 °C

3: 98 percent / NaBH₄ / methanol / 2 h / Ambient temperature

4: 98.7 percent / diisopropylethylamine / tetrahydrofuran / Ambient temperature

With sodium tetrahydroborate; boron trifluoride diethyl etherate; diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; dichloromethane; toluene;
DOI:10.1021/jo00232a032

Reference yield:

: 110417-00-0
1-methoxy-4-(3,4-dimethoxyphenyl)cyclohexa-1,3-diene

: 110417-14-6
1,1-(ethylenedithio)-4-<2-(methoxymethoxy)ethyl>-4-(3,4-dimethoxyphenyl)cyclohex-2-ene

Guidance literature:: Multi-step reaction with 8 steps

1: 25.8 percent / phenothiazine / toluene / 5 h / 180 °C

2: 37 percent / Na₂S*9H₂O / ethanol / 42 h / Heating

3: 100 percent / hydroxylamine hydrochloride, sodium acetate / methanol; H₂O / Heating

4: 91 percent / triethylamine, mesyl chloride / CH₂Cl₂ / 3 h / Ambient temperature

5: 92 percent / boron trifluoride etherate / CH₂Cl₂ / 2 h / 0 °C

6: 94.5 percent / diisobutylaluminum hydride / toluene / 1 h / -78 °C

7: 98 percent / NaBH₄ / methanol / 2 h / Ambient temperature

8: 98.7 percent / diisopropylethylamine / tetrahydrofuran / Ambient temperature

With sodium sulfide; sodium tetrahydroborate; 10H-phenothiazine; boron trifluoride diethyl etherate; hydroxylamine hydrochloride; sodium acetate; diisobutylaluminium hydride; methanesulfonyl chloride; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; toluene;
DOI:10.1021/jo00232a032