ethyl (1RS,6SR)-<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate

Base Information

Chemical Name:ethyl (1RS,6SR)-<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate
CAS No.:119414-48-1
Molecular Formula:C₂₂H₄₄O₄Si₂
Molecular Weight:428.76
Hs Code.:

Synonyms:ethyl (1RS,6SR)-<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate

Suppliers and Price of ethyl (1RS,6SR)-<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ethyl (1RS,6SR)-<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate

Chemical Property:

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Technology Process of ethyl (1RS,6SR)-<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate

There total 8 articles about ethyl (1RS,6SR)-<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4096-34-8
cyclohex-3-enone

: 119414-48-1
ethyl (1RS,6SR)-<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate

Guidance literature:: Multi-step reaction with 4 steps

1: mCPBA / CH₂Cl₂ / 14 h / Ambient temperature

2: basic alumina / CH₂Cl₂; diethyl ether / 1 h

3: 92 percent / DBU / benzene / 1.5 h / Ambient temperature

4: 1.) HgI₂ / 1.) room temp., 15 min, 2.) - 78 deg C, 2 h

With aluminum oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid; mercury(II) iodide; In diethyl ether; dichloromethane; benzene;
DOI:10.1021/ja00189a038

Reference yield:

: 4096-34-8
cyclohex-3-enone

: 119414-48-1,119478-64-7
ethyl (1RS,6RS)<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate

Guidance literature:: Multi-step reaction with 4 steps

1: mCPBA / CH₂Cl₂ / 14 h / Ambient temperature

2: basic alumina / CH₂Cl₂; diethyl ether / 1 h

3: 92 percent / DBU / benzene / 1.5 h / Ambient temperature

4: 1.) HgI₂ / 1.) room temp., 15 min, 2.) - 78 deg C, 2 h

With aluminum oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid; mercury(II) iodide; In diethyl ether; dichloromethane; benzene;
DOI:10.1021/ja00189a038

Reference yield:

: 30182-12-8
4-hydroxy-2-cyclohexenone

: 119414-48-1,119478-64-7
ethyl (1RS,6RS)<3,6-bis(tert-butyldimethylsiloxy)-2-cyclohexen-1-yl>acetate

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / DBU / benzene / 1.5 h / Ambient temperature

2: 1.) HgI₂ / 1.) room temp., 15 min, 2.) - 78 deg C, 2 h

With 1,8-diazabicyclo[5.4.0]undec-7-ene; mercury(II) iodide; In benzene;
DOI:10.1021/ja00189a038