Trifluoro-methanesulfonatebis-(4'-bromo-biphenyl-4-yl)-iodonium;

Base Information

• Chemical Name: Trifluoro-methanesulfonatebis-(4'-bromo-biphenyl-4-yl)-iodonium
• CAS No.: 139139-83-6
• Molecular Formula: CF₃O₃S*C₂₄H₁₆Br₂I
• Molecular Weight: 740.174
• Mol file: 139139-83-6.mol

Synonyms:Trifluoro-methanesulfonatebis-(4'-bromo-biphenyl-4-yl)-iodonium;

Chemical Property of Trifluoro-methanesulfonatebis-(4'-bromo-biphenyl-4-yl)-iodonium;

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Trifluoro-methanesulfonatebis-(4'-bromo-biphenyl-4-yl)-iodonium;

There total 1 articles about Trifluoro-methanesulfonatebis-(4'-bromo-biphenyl-4-yl)-iodonium; which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

(4′-bromobiphenyl-4-yl)(trimethyl)silane (17908-91-7) + iodosyl trifluoromethanesulfonate (58735-50-5) → Trifluoro-methanesulfonatebis-(4'-bromo-biphenyl-4-yl)-iodonium; (139139-83-6)

Guidance literature:

In dichloromethane; 1) -78 deg C -> rt, 2) rt, 30 min;

DOI:10.1016/0040-4039(91)80516-9

Reference yield: 56.0%

benzofurazan (273-09-6) + Trifluoro-methanesulfonatebis-(4'-bromo-biphenyl-4-yl)-iodonium; (139139-83-6) → 3-(4-bromophenyl)phenazine 5-oxide

Guidance literature:

With copper(I) bromide; In 1,2-dichloro-ethane; at 70 ℃; for 24h; regioselective reaction; Sealed tube; Inert atmosphere;

DOI:10.1021/acs.orglett.8b01748

upstream raw materials:

(4′-bromobiphenyl-4-yl)(trimethyl)silane

iodosyl trifluoromethanesulfonate