Technology Process of bis[(R(S),R(P))-2-(tert-butylsulfinyl)ferrocenyl](p-methoxyphenyl)methanol
There total 1 articles about bis[(R(S),R(P))-2-(tert-butylsulfinyl)ferrocenyl](p-methoxyphenyl)methanol which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
t-BuLi;
In
tetrahydrofuran; pentane;
soln. of t-BuLi in pentane was added dropwise to soln. of Fe complex in THF at -78°C; mixt. was stirred at -78°C for 1.5 h; soln. of ether in THF was added; mixt. was kept at -78°C; brine added; aq. layer extd. (EtOAc); combined org. layers dried (MgSO4); solvent evapd.; residue chromd. (hexane/Et2O, 1/6); elem. anal.;
DOI:10.1021/om049924b