2-(4’-hydroxyphenyl)-1-phenylimidazo[4,5-f]-1,10-phenanthroline

Base Information

• Chemical Name: 2-(4’-hydroxyphenyl)-1-phenylimidazo[4,5-f]-1,10-phenanthroline
• CAS No.: 1313372-55-2
• Molecular Formula: C₂₅H₁₆N₄O
• Molecular Weight: 388.428
• Mol file: 1313372-55-2.mol

Synonyms:2-(4’-hydroxyphenyl)-1-phenylimidazo[4,5-f]-1,10-phenanthroline

Chemical Property of 2-(4’-hydroxyphenyl)-1-phenylimidazo[4,5-f]-1,10-phenanthroline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(4’-hydroxyphenyl)-1-phenylimidazo[4,5-f]-1,10-phenanthroline

There total 2 articles about 2-(4’-hydroxyphenyl)-1-phenylimidazo[4,5-f]-1,10-phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

1,10-phenanthroline-5,6-dione (27318-90-7) + 4-hydroxy-benzaldehyde (123-08-0,65581-83-1) + aniline (62-53-3) → 2-(4’-hydroxyphenyl)-1-phenylimidazo[4,5-f]-1,10-phenanthroline (1313372-55-2)

Guidance literature:

With ammonium acetate; In acetic acid; for 24h; Reflux; Inert atmosphere;

DOI:10.1002/cplu.201402006

Reference yield:

1,10-Phenanthroline (66-71-7) → 2-(4’-hydroxyphenyl)-1-phenylimidazo[4,5-f]-1,10-phenanthroline (1313372-55-2)

Guidance literature:

Multi-step reaction with 2 steps

1: nitric acid; sulfuric acid; potassium bromide / 6 h / Reflux

2: ammonium acetate / acetic acid / 24 h / Reflux; Inert atmosphere

With sulfuric acid; ammonium acetate; nitric acid; potassium bromide; In acetic acid;

DOI:10.1002/cplu.201402006

Reference yield: 93.0%

dichloro(4,4'-bis(ethylcarboxy)-2,2'-bipyridine)2ruthenium(II) (70281-20-8) + 2-(4’-hydroxyphenyl)-1-phenylimidazo[4,5-f]-1,10-phenanthroline (1313372-55-2) + sodium triflate (2926-30-9) → 2CF3O3S(1-)*C57H48N8O9Ru(2+)

Guidance literature:

dichloro(4,4'-bis(ethylcarboxy)-2,2'-bipyridine)2ruthenium(II); 2-(4’-hydroxyphenyl)-1-phenylimidazo[4,5-f]-1,10-phenanthroline; In ethanol; at 120 ℃; for 19h;

sodium triflate; In water; at 100 ℃; for 1h;

DOI:10.1002/cplu.201402006

upstream raw materials:

1,10-phenanthroline-5,6-dione

4-hydroxy-benzaldehyde

aniline

1,10-Phenanthroline