<2R-(2α,4aβ,5β,6α,7aβ)>-Hexahydro-5-methyl-2-phenyl-6-(phenylmethoxy)cyclopenta-1,3-dioxin

Base Information

Chemical Name:<2R-(2α,4aβ,5β,6α,7aβ)>-Hexahydro-5-methyl-2-phenyl-6-(phenylmethoxy)cyclopenta-1,3-dioxin
CAS No.:119111-18-1
Molecular Formula:C₂₁H₂₄O₃
Molecular Weight:324.42
Hs Code.:

Synonyms:<2R-(2α,4aβ,5β,6α,7aβ)>-Hexahydro-5-methyl-2-phenyl-6-(phenylmethoxy)cyclopenta-1,3-dioxin

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Chemical Property of <2R-(2α,4aβ,5β,6α,7aβ)>-Hexahydro-5-methyl-2-phenyl-6-(phenylmethoxy)cyclopenta-1,3-dioxin

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Technology Process of <2R-(2α,4aβ,5β,6α,7aβ)>-Hexahydro-5-methyl-2-phenyl-6-(phenylmethoxy)cyclopenta-1,3-dioxin

There total 3 articles about <2R-(2α,4aβ,5β,6α,7aβ)>-Hexahydro-5-methyl-2-phenyl-6-(phenylmethoxy)cyclopenta-1,3-dioxin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 119111-17-0
(2R,4S,5R)-4-((R)-2-Benzyloxy-but-3-enyl)-2-phenyl-[1,3]dioxan-5-ol

: 119111-18-1
<2R-(2α,4aβ,5β,6α,7aβ)>-Hexahydro-5-methyl-2-phenyl-6-(phenylmethoxy)cyclopenta-1,3-dioxin

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂ / 2 h / Heating

2: AIBN, Bu₃SnH / toluene / 3 h / Heating

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In dichloromethane; toluene;
DOI:10.1021/ja00187a031

Reference yield:

: 115859-25-1,115859-26-2
3-deoxy-2-O-(phenylmethyl)-4,6-O-(phenylmethylene)-D-ribo-hexopyranose

: 119111-18-1
<2R-(2α,4aβ,5β,6α,7aβ)>-Hexahydro-5-methyl-2-phenyl-6-(phenylmethoxy)cyclopenta-1,3-dioxin

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) THF, hexane, -20 deg C --> room temp., 1h, 2.) -20 deg C --> room temp., 16h, 3.) 50 deg C, 15 min

2: CH₂Cl₂ / 2 h / Heating

3: AIBN, Bu₃SnH / toluene / 3 h / Heating

With n-butyllithium; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In dichloromethane; toluene;
DOI:10.1021/ja00187a031

Reference yield:

: Imidazole-1-carbothioic acid O-[(2R,4S,5R)-4-((R)-2-benzyloxy-but-3-enyl)-2-phenyl-[1,3]dioxan-5-yl] ester

: 119237-83-1
(2R,4aS,5S,6R,7aS)-6-Benzyloxy-5-methyl-2-phenyl-hexahydro-cyclopenta[1,3]dioxine

: 119111-18-1
<2R-(2α,4aβ,5β,6α,7aβ)>-Hexahydro-5-methyl-2-phenyl-6-(phenylmethoxy)cyclopenta-1,3-dioxin

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene; for 3h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Heating;
DOI:10.1021/ja00187a031