(1aS,8R,9aS*)-4,7-dibenzyloxy-6-methoxy-5,8-dimethyl-9-oxo-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine

Base Information

Chemical Name:(1aS*,8R*,9aS*)-4,7-dibenzyloxy-6-methoxy-5,8-dimethyl-9-oxo-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine
CAS No.:129056-07-1
Molecular Formula:C₄₂H₄₂N₂O₈S₂
Molecular Weight:766.936
Hs Code.:

Synonyms:(1aS*,8R*,9aS*)-4,7-dibenzyloxy-6-methoxy-5,8-dimethyl-9-oxo-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1aS*,8R*,9aS*)-4,7-dibenzyloxy-6-methoxy-5,8-dimethyl-9-oxo-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine

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Technology Process of (1aS*,8R*,9aS*)-4,7-dibenzyloxy-6-methoxy-5,8-dimethyl-9-oxo-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine

There total 1 articles about (1aS*,8R*,9aS*)-4,7-dibenzyloxy-6-methoxy-5,8-dimethyl-9-oxo-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 129077-33-4
(1aS*,8R*,9R*,9aS*)-4,7-dibenzyloxy-9-hydroxy-6-methoxy-5,8-dimethyl-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine

: 129056-07-1
(1aS*,8R*,9aS*)-4,7-dibenzyloxy-6-methoxy-5,8-dimethyl-9-oxo-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; for 4h; Ambient temperature;
DOI:10.1039/c39900000468

Reference yield: 100.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 129056-07-1
(1aS*,8R*,9aS*)-4,7-dibenzyloxy-6-methoxy-5,8-dimethyl-9-oxo-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine

: 129077-34-5
(1aS*,8R*,8aR*,8bS*)-4,7-dibenzyloxy-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-1-p-toluenesulfonyl-1,1a,2,8,8a,8b-hexahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole

Guidance literature:: With triethylamine; In dichloromethane; at -78 - 25 ℃;
DOI:10.1039/c39900000468

Reference yield:

: 129056-07-1
(1aS*,8R*,9aS*)-4,7-dibenzyloxy-6-methoxy-5,8-dimethyl-9-oxo-1,3-bis(p-toluenesulfonyl)-1a,2,3,8,9,9a-hexahydro-1H-azirino<2,3-c><1>benzazocine

: 129056-08-2
(1aS*,8R*,8aR*,8bS*)-8a-tert-butyldimethylsiloxy-6-methoxy-5,8-dimethyl-4,7-dioxo-1-p-toluenesulfonyl-1,1a,2,4,7,8,8a,8b-octahydroazirino<2',3':3,4>pyrrolo<1,2-a>indole

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / Et₃N / CH₂Cl₂ / 0.17 h / Ambient temperature

2: H₂ / 10percent Pd/C / ethyl acetate / 0.17 h / Ambient temperature

3: O₂ / ethyl acetate / 0.17 h / Ambient temperature

With hydrogen; oxygen; triethylamine; palladium on activated charcoal; In dichloromethane; ethyl acetate;