(1aα,4β,4aβ,7α,7aα,7bα)-1a,2,3,4,4a,7,7a,7b-octahydro-4,7a-dimethyl-7-(phenylmethoxy)azuleno<4,5-b>oxiren-2-ol

Base Information

Chemical Name:(1aα,4β,4aβ,7α,7aα,7bα)-1a,2,3,4,4a,7,7a,7b-octahydro-4,7a-dimethyl-7-(phenylmethoxy)azuleno<4,5-b>oxiren-2-ol
CAS No.:68306-73-0
Molecular Formula:C₁₉H₂₄O₃
Molecular Weight:300.398
Hs Code.:

Synonyms:(1aα,4β,4aβ,7α,7aα,7bα)-1a,2,3,4,4a,7,7a,7b-octahydro-4,7a-dimethyl-7-(phenylmethoxy)azuleno<4,5-b>oxiren-2-ol

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Chemical Property of (1aα,4β,4aβ,7α,7aα,7bα)-1a,2,3,4,4a,7,7a,7b-octahydro-4,7a-dimethyl-7-(phenylmethoxy)azuleno<4,5-b>oxiren-2-ol

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Technology Process of (1aα,4β,4aβ,7α,7aα,7bα)-1a,2,3,4,4a,7,7a,7b-octahydro-4,7a-dimethyl-7-(phenylmethoxy)azuleno<4,5-b>oxiren-2-ol

There total 40 articles about (1aα,4β,4aβ,7α,7aα,7bα)-1a,2,3,4,4a,7,7a,7b-octahydro-4,7a-dimethyl-7-(phenylmethoxy)azuleno<4,5-b>oxiren-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 68241-55-4
(1aα,4β,4aβ,7α,7aα,7bα)-3,4,4a,7,7a,7b-hexahydro-4,7a-dimethyl-7-(phenylmethoxy)azuleno<4,5-b>oxiren-2(1aH)-one

: 68306-73-0
(1aα,4β,4aβ,7α,7aα,7bα)-1a,2,3,4,4a,7,7a,7b-octahydro-4,7a-dimethyl-7-(phenylmethoxy)azuleno<4,5-b>oxiren-2-ol

Guidance literature:: With sodium tetrahydroborate; In ethanol; at 0 ℃; for 1h;
DOI:10.1021/ja00379a030

Reference yield: 65.0%

: 70913-22-3
(1α,3aβ,4β,8aα)-3a,4,5,8a-Tetrahydro-4,8a-dimethyl-1-(phenylmethoxy)-6(1H)-azulenol

: 68306-73-0,70981-14-5
(1aα,2β,4β,4aβ,7α,7aα,7bα)-1a,2,3,4,4a,7,7a,7b-Octahydro-4,7a-dimethyl-7-(phenylmethoxy)azuleno<4,5-b>oxiren-2-ol

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 17h; Ambient temperature;
DOI:10.1021/jo00151a016

Reference yield:

: 68241-54-3
(1α,3aβ,4β,8aα)-3a,4,5,8a-Tetrahydro-4,8a-dimethyl-1-(phenylmethoxy)-6(1H)-azulenone

: 68306-73-0,70981-14-5
(1aα,2β,4β,4aβ,7α,7aα,7bα)-1a,2,3,4,4a,7,7a,7b-Octahydro-4,7a-dimethyl-7-(phenylmethoxy)azuleno<4,5-b>oxiren-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1: LiAlH₄

2: MCPBA / CH₂Cl₂

With lithium aluminium tetrahydride; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/ja00379a030