(3S)-1-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-3-hexanol

Base Information

• Chemical Name: (3S)-1-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-3-hexanol
• CAS No.: 264194-80-1
• Molecular Formula: C₂₂H₃₂O₂S
• Molecular Weight: 360.561
• Mol file: 264194-80-1.mol

Synonyms:(3S)-1-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-3-hexanol

Chemical Property of (3S)-1-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-3-hexanol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (3S)-1-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-3-hexanol

There total 1 articles about (3S)-1-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-3-hexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

(E)-1-phenylhex-1-en-3-one (82297-62-9) + (1S,2R,4R)-(-)-10-mercaptoisoboneol (71242-58-5) → (3S)-1-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-3-hexanol (264194-80-1)

Guidance literature:

With dimethyl aluminum hydride; In hexane; dichloromethane; at 20 ℃; for 16h;

DOI:10.1021/ja993546y

Reference yield: 95.0%

(3S)-1-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-3-hexanol (264194-80-1) → (+)-1-Phenyl-hexan-3-ol (134627-14-8)

Guidance literature:

With sodium hypophosphite; nickel; In ethanol; acetate buffer; at 20 ℃; for 0.333333h; pH=5.2;

DOI:10.1021/ja993546y

Reference yield:

(3S)-1-[(1S,4R)-2-oxobornane-10-sulfenyl]-1-phenyl-3-hexanol (264194-80-1) → (1S,2R,4R)-1-((1R,3S)-3-Hydroxy-1-phenyl-hexylsulfanylmethyl)-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 20 ℃; for 2h;

DOI:10.1016/j.tetasy.2004.01.020

upstream raw materials:

(E)-1-phenylhex-1-en-3-one

(1S,2R,4R)-(-)-10-mercaptoisoboneol

Downstream raw materials:

(+)-1-Phenyl-hexan-3-ol