dimethyl (cis)-1,2-di(trimethylsilylmethyl)-4,5-cyclohexenedicarboxylate

Base Information

Chemical Name:dimethyl (cis)-1,2-di(trimethylsilylmethyl)-4,5-cyclohexenedicarboxylate
CAS No.:82167-61-1
Molecular Formula:C₁₈H₃₄O₄Si₂
Molecular Weight:370.637
Hs Code.:

Synonyms:dimethyl (cis)-1,2-di(trimethylsilylmethyl)-4,5-cyclohexenedicarboxylate

Suppliers and Price of dimethyl (cis)-1,2-di(trimethylsilylmethyl)-4,5-cyclohexenedicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dimethyl (cis)-1,2-di(trimethylsilylmethyl)-4,5-cyclohexenedicarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of dimethyl (cis)-1,2-di(trimethylsilylmethyl)-4,5-cyclohexenedicarboxylate

There total 2 articles about dimethyl (cis)-1,2-di(trimethylsilylmethyl)-4,5-cyclohexenedicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 82167-48-4
2,3-bis<(trimethyksilyl)methyl>-1,3-butadiene

: 624-48-6
dimethyl cis-but-2-ene-1,4-dioate

: 82167-61-1
dimethyl (cis)-1,2-di(trimethylsilylmethyl)-4,5-cyclohexenedicarboxylate

Guidance literature:: With aluminium trichloride; In dichloromethane; Ambient temperature;
DOI:10.1021/ja00379a066

Reference yield:

: 81790-10-5
(2-bromoallyl)trimethylsilane

: 82167-61-1
dimethyl (cis)-1,2-di(trimethylsilylmethyl)-4,5-cyclohexenedicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: .) t-BuLi, 2.) CuI, CuCl₂ / 1.) ether, -78 deg C, 1 h; -23 deg C, 1 h, 2.) -78 deg C, 1 h; -23 deg C, 30 min; -23 deg C, 1 h; room temperature, 15 h

2: 63 percent / AlCl₃ / CH₂Cl₂ / Ambient temperature

With copper(l) iodide; aluminium trichloride; tert.-butyl lithium; copper dichloride; In dichloromethane;
DOI:10.1021/ja00379a066

Reference yield:

: 82167-61-1
dimethyl (cis)-1,2-di(trimethylsilylmethyl)-4,5-cyclohexenedicarboxylate

: 107124-00-5
(1S,2R)-4,5-Dimethylene-cyclohexane-1,2-dicarboxylic acid dimethyl ester

Guidance literature:: With N-Bromosuccinimide; methyloxirane; In tetrahydrofuran; 1.) -100 deg C, 10 min, 2.) -78 deg C, 1 h;
DOI:10.1021/ja00379a066