Methyl <4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoate

Base Information

Chemical Name:Methyl <4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoate
CAS No.:165605-97-0
Molecular Formula:C₂₅H₃₄O₄
Molecular Weight:398.543
Hs Code.:

Synonyms:Methyl <4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoate

Suppliers and Price of Methyl <4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methyl <4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methyl <4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoate

There total 10 articles about Methyl <4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 165605-96-9
<4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-Methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoic acid

: 165605-97-0
Methyl <4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoate

Guidance literature:: In diethyl ether;
DOI:10.1021/jo00122a037

Reference yield:

: 165605-95-8
<4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-Methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanal

: 165605-97-0
Methyl <4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / aq. NaClO₂, aq. NaH₂PO₄, 2-methyl-2-butene / 2-methyl-propan-2-ol / 1.) 0 deg C, 10 min, 2.) r.t., 1 h

2: 79 percent / diethyl ether

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; In diethyl ether; tert-butyl alcohol;
DOI:10.1021/jo00122a037

Reference yield:

: 165605-92-5
<4S-<4α,5α(4S*,6R*),6β>>-5-<2-<6-<2-<<(1,1-Dimethylethyl)diphenylsilyl>oxy>ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethyl>-4-methyl-6-phenyl-2-cyclohexen-1-one

: 165605-97-0
Methyl <4R-<4α,6α(1αS*,2α,6β)>>-<6-<2-(2-methyl-5-methylene-6-phenyl-3-cyclohexen-1-yl)ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethanoate

Guidance literature:: Multi-step reaction with 5 steps

1: 81 percent / tetrahydrofuran; toluene / 0.5 h

2: 97 percent / TBAF / tetrahydrofuran / 1.) -78 deg C, 30 min, 2.) r.t., 16 h

3: 1.) DMSO, (COCl)2, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 20 min, 2.) -78 deg C, 10 min; r.t., 20 min

4: 94 percent / aq. NaClO₂, aq. NaH₂PO₄, 2-methyl-2-butene / 2-methyl-propan-2-ol / 1.) 0 deg C, 10 min, 2.) r.t., 1 h

5: 79 percent / diethyl ether

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; oxalyl dichloride; tetrabutyl ammonium fluoride; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; diethyl ether; toluene; tert-butyl alcohol;
DOI:10.1021/jo00122a037