(4aS,11cR)-1-(2-Benzenesulfinyl-ethyl)-4a-ethyl-7-(4-methoxy-benzenesulfonyl)-5,6,7,11c-tetrahydro-1H,4aH-pyrido[3,2-c]carbazol-2-one

Base Information

Chemical Name:(4aS,11cR)-1-(2-Benzenesulfinyl-ethyl)-4a-ethyl-7-(4-methoxy-benzenesulfonyl)-5,6,7,11c-tetrahydro-1H,4aH-pyrido[3,2-c]carbazol-2-one
CAS No.:87393-31-5
Molecular Formula:C₃₂H₃₂N₂O₅S₂
Molecular Weight:588.748
Hs Code.:

Synonyms:(4aS,11cR)-1-(2-Benzenesulfinyl-ethyl)-4a-ethyl-7-(4-methoxy-benzenesulfonyl)-5,6,7,11c-tetrahydro-1H,4aH-pyrido[3,2-c]carbazol-2-one

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Chemical Property of (4aS,11cR)-1-(2-Benzenesulfinyl-ethyl)-4a-ethyl-7-(4-methoxy-benzenesulfonyl)-5,6,7,11c-tetrahydro-1H,4aH-pyrido[3,2-c]carbazol-2-one

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Technology Process of (4aS,11cR)-1-(2-Benzenesulfinyl-ethyl)-4a-ethyl-7-(4-methoxy-benzenesulfonyl)-5,6,7,11c-tetrahydro-1H,4aH-pyrido[3,2-c]carbazol-2-one

There total 4 articles about (4aS,11cR)-1-(2-Benzenesulfinyl-ethyl)-4a-ethyl-7-(4-methoxy-benzenesulfonyl)-5,6,7,11c-tetrahydro-1H,4aH-pyrido[3,2-c]carbazol-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 87372-39-2
cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-one

: 87393-31-5
(4aS,11cR)-1-(2-Benzenesulfinyl-ethyl)-4a-ethyl-7-(4-methoxy-benzenesulfonyl)-5,6,7,11c-tetrahydro-1H,4aH-pyrido[3,2-c]carbazol-2-one

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/ja00359a047

Reference yield:

: 87372-37-0
cis-4a-ethyl-1,3,4,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-thione

: 87393-31-5
(4aS,11cR)-1-(2-Benzenesulfinyl-ethyl)-4a-ethyl-7-(4-methoxy-benzenesulfonyl)-5,6,7,11c-tetrahydro-1H,4aH-pyrido[3,2-c]carbazol-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / p-toluenesulfinyl chloride, i-Pr₂NEt / CH₂Cl₂ / 6 h / 20 °C

2: 57 percent / Et₃O(+)*BF₄(-) / CH₂Cl₂ / 10 min, 0 deg C then 1 h, 25 deg C

3: 117 mg / 10percent aq. NaHCO₃, MCPBA / CH₂Cl₂ / 0.5 h / 0 °C

With 4-methylbenzenesulfinyl chloride; triethyloxonium fluoroborate; sodium hydrogencarbonate; N-ethyl-N,N-diisopropylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/ja00262a005

Reference yield:

: 87393-13-3
cis-4a-ethyl-1,4a,5,6,7,11c-octahydro-7-<(p-methoxyphenyl)sulfonyl>-1-<2-(phenylthio)ethyl>-2H-pyrido<3,2-c>carbazol-2-thione

: 87393-31-5
(4aS,11cR)-1-(2-Benzenesulfinyl-ethyl)-4a-ethyl-7-(4-methoxy-benzenesulfonyl)-5,6,7,11c-tetrahydro-1H,4aH-pyrido[3,2-c]carbazol-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: 57 percent / Et₃O(+)*BF₄(-) / CH₂Cl₂ / 10 min, 0 deg C then 1 h, 25 deg C

2: 117 mg / 10percent aq. NaHCO₃, MCPBA / CH₂Cl₂ / 0.5 h / 0 °C

With triethyloxonium fluoroborate; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/ja00262a005