bis{tris(neopentyl)rhodium(IV)}μ-oxo

Base Information

Chemical Name:bis{tris(neopentyl)rhodium(IV)}μ-oxo
CAS No.:132030-92-3
Molecular Formula:C₃₀H₆₆ORh₂
Molecular Weight:648.664
Hs Code.:

Synonyms:bis{tris(neopentyl)rhodium(IV)}μ-oxo

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Chemical Property of bis{tris(neopentyl)rhodium(IV)}μ-oxo

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Technology Process of bis{tris(neopentyl)rhodium(IV)}μ-oxo

There total 2 articles about bis{tris(neopentyl)rhodium(IV)}μ-oxo which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 35933-36-9,52611-16-2
RhCl₃(tetrahydrothiophen)3

: 7412-67-1
neopentyl lithium

: 132030-92-3
bis{tris(neopentyl)rhodium(IV)}μ-oxo

Guidance literature:: With O₂; In diethyl ether; addn. of dry O2 to soln. of (CH3)3CCH2Li in Et2O at -78°C (inert atmosphere); warming to room temp.; re-cooling to -78°C when addn. to suspension of Rh-complex in Et2O; vigorous stirring; warming to room temp. (1h); removing volatiles in vac.; extg. residue (hexane); filtration; concg. filtrate; cooling to -30°C; crystn. (hexane); elem. anal.;
DOI:10.1016/S0277-5387(00)84038-3

Reference yield: 30.0%

: 35933-36-9,52611-16-2
RhCl₃(tetrahydrothiophen)3

: 1184-78-7
trimethylamine-N-oxide

: 7412-67-1
neopentyl lithium

: 132030-92-3
bis{tris(neopentyl)rhodium(IV)}μ-oxo

Guidance literature:: In diethyl ether; addn. of four-fold excess of neopentyllithium plus two-fold excess of Me3NO in Et2O to RhCl3(C4H8S)3 at -78°C (inert atmosphere);
DOI:10.1016/S0277-5387(00)84038-3