1α-<<(2,5-dimethoxybenzyl)oxy>methyl>-5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohexan-2-one

Base Information

Chemical Name:1α-<<(2,5-dimethoxybenzyl)oxy>methyl>-5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohexan-2-one
CAS No.:177284-85-4
Molecular Formula:C₁₉H₂₆O₈
Molecular Weight:382.411
Hs Code.:

Synonyms:1α-<<(2,5-dimethoxybenzyl)oxy>methyl>-5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohexan-2-one

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Chemical Property of 1α-<<(2,5-dimethoxybenzyl)oxy>methyl>-5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohexan-2-one

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Technology Process of 1α-<<(2,5-dimethoxybenzyl)oxy>methyl>-5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohexan-2-one

There total 5 articles about 1α-<<(2,5-dimethoxybenzyl)oxy>methyl>-5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohexan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 177284-84-3
1α-<<(2,5-dimethoxybenzyl)oxy>methyl>-5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohexan-2β-ol

: 177284-85-4
1α-<<(2,5-dimethoxybenzyl)oxy>methyl>-5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohexan-2-one

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; for 24h;
DOI:10.1021/jo952132u

Reference yield:

: 40983-58-2
methyl shikimate

: 177284-85-4
1α-<<(2,5-dimethoxybenzyl)oxy>methyl>-5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohexan-2-one

Guidance literature:: Multi-step reaction with 5 steps

1: 85 percent / P₂O₅ / CHCl₃ / 20 h / Ambient temperature

2: 6.47 g / diisobutylaluminum hydride / tetrahydrofuran; hexane

3: 5.1 g / sodium hydride / tetrahydrofuran / 6 h / Heating

4: 1.) BH₃*THF, 2.) H₂O₂, NaOH / 1.) THF, 0 deg C, 1.7 h, 2.) water, heating

5: 78 percent / pyridinium chlorochromate / CH₂Cl₂ / 24 h

With sodium hydroxide; borane-THF; dihydrogen peroxide; phosphorus pentoxide; sodium hydride; diisobutylaluminium hydride; pyridinium chlorochromate; In tetrahydrofuran; hexane; dichloromethane; chloroform;
DOI:10.1021/jo952132u

Reference yield:

: 177284-82-1
5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohex-1-enemethanol

: 177284-85-4
1α-<<(2,5-dimethoxybenzyl)oxy>methyl>-5β-(methoxymethoxy)-3α,4α-(methylenedioxy)cyclohexan-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: 5.1 g / sodium hydride / tetrahydrofuran / 6 h / Heating

2: 1.) BH₃*THF, 2.) H₂O₂, NaOH / 1.) THF, 0 deg C, 1.7 h, 2.) water, heating

3: 78 percent / pyridinium chlorochromate / CH₂Cl₂ / 24 h

With sodium hydroxide; borane-THF; dihydrogen peroxide; sodium hydride; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo952132u