1-Isocyanobicyclo[2.2.1]heptane

Base Information

Chemical Name:1-Isocyanobicyclo[2.2.1]heptane
CAS No.:103434-09-9
Molecular Formula:C₈H₁₁N
Molecular Weight:121.182
Hs Code.:
DSSTox Substance ID:DTXSID50908406
Wikidata:Q82877810
Mol file:103434-09-9.mol

Synonyms:1-isocyanobicyclo[2.2.1]heptane;DTXSID50908406

Suppliers and Price of 1-Isocyanobicyclo[2.2.1]heptane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
BICYCLO[2.2.1]HEPTANE-1-CARBONITRILE 95.00%
5MG
$ 498.95

Total 2 raw suppliers

Chemical Property of 1-Isocyanobicyclo[2.2.1]heptane

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：23.79000
Density:g/cm³
LogP:2.09028
XLogP3:1.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:121.089149355
Heavy Atom Count:9
Complexity:166

Purity/Quality:: BICYCLO[2.2.1]HEPTANE-1-CARBONITRILE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[C-]#[N+]C12CCC(C1)CC2

Technology Process of 1-Isocyanobicyclo[2.2.1]heptane

There total 2 articles about 1-Isocyanobicyclo[2.2.1]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69095-03-0
norbornane-1-carboxamide

: 103434-09-9
bicyclo<2.2.1>heptane-1-carbonitrile

Guidance literature:: With pyridine; trifluoroacetic anhydride; In 1,4-dioxane; Ambient temperature;

Reference yield:

: 88523-51-7
1-bicyclo<2.2.1>heptyl isocyanide

: 103434-09-9
bicyclo<2.2.1>heptane-1-carbonitrile

Guidance literature:: With 1,1-Diphenylethylene; In various solvent(s); at 210 ℃; Rate constant; Thermodynamic data; ΔG(excit.) <250 deg C>; ΔH(excit.), ΔS(excit.);
DOI:10.1021/jo00380a028

Reference yield:

: 103434-09-9
bicyclo<2.2.1>heptane-1-carbonitrile

: 100084-01-3
2,2-dimethyl-1-(1-norbornyl)-1-propanone triphenylphosphoranylidenehydrazone

Guidance literature:: Multi-step reaction with 3 steps

1: 81 percent / benzene; pentane / 4 h / 25 °C

2: 62 percent / 100percent hydrazine hydrate, 2 N H₂SO₄ / 36 h / Heating

3: 1.) Br₂, 2.) triethylamine / 1.) benzene, room temp., 30 min, 2.) 5 h

With sulfuric acid; bromine; hydrazine hydrate; triethylamine; In pentane; benzene;