dichlorobis(dimethylphenylphosphine)(methylphenylphosphinmethyl-C₁P)iridium(III)

Base Information

• Chemical Name: dichlorobis(dimethylphenylphosphine)(methylphenylphosphinmethyl-C₁P)iridium(III)
• CAS No.: 79469-85-5
• Molecular Formula: C₂₄H₃₂Cl₂IrP₃
• Molecular Weight: 676.565
• Mol file: 79469-85-5.mol

Synonyms:dichlorobis(dimethylphenylphosphine)(methylphenylphosphinmethyl-C₁P)iridium(III)

Chemical Property of dichlorobis(dimethylphenylphosphine)(methylphenylphosphinmethyl-C₁P)iridium(III)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of dichlorobis(dimethylphenylphosphine)(methylphenylphosphinmethyl-C₁P)iridium(III)

There total 1 articles about dichlorobis(dimethylphenylphosphine)(methylphenylphosphinmethyl-C₁P)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

mer-IrCl3(PMe2Ph)3 (15613-31-7,15664-86-5,21919-29-9) → dichlorobis(dimethylphenylphosphine)(methylphenylphosphinmethyl-C1P)iridium(III) (79469-85-5)

Guidance literature:

With lithium di-isopropylamide; In diethyl ether; addn. at 0°C, stirring for 10 min at 0°C; addn. of water, isolation from organic layer, crystn. from methanol; elem. anal.;

DOI:10.1039/DT9810001572

Reference yield: 72.0%

dichlorobis(dimethylphenylphosphine)(methylphenylphosphinmethyl-C1P)iridium(III) (79469-85-5) → mer-[IrCl3(PMe2Ph)2[PMePh(CH2Cl)]] (79160-61-5,79200-34-3)

Guidance literature:

With chlorine; In tetrachloromethane; addn. at 0°C then warming to room temp.; product was sepd., filtered off, recrystn. from CH2Cl2/methanol; elem. anal.;

DOI:10.1039/DT9810001572

upstream raw materials:

mer-IrCl₃(PMe₂Ph)3

Downstream raw materials:

mer-[IrCl₃(PMe₂Ph)2[PMePh(CH₂Cl)]]