(CH₃C(CH₂P(C₆H₅)2)3)Ni(CS₂)

Base Information

• Chemical Name: (CH₃C(CH₂P(C₆H₅)2)3)Ni(CS₂)
• CAS No.: 60294-99-7
• Molecular Formula: C₄₂H₃₉NiP₃S₂
• Molecular Weight: 759.515
• Mol file: 60294-99-7.mol

Synonyms:(CH₃C(CH₂P(C₆H₅)2)3)Ni(CS₂)

Chemical Property of (CH₃C(CH₂P(C₆H₅)2)3)Ni(CS₂)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (CH₃C(CH₂P(C₆H₅)2)3)Ni(CS₂)

There total 5 articles about (CH₃C(CH₂P(C₆H₅)2)3)Ni(CS₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S2CSMe)]BPh4 (83561-95-9) → (CH3C(CH2P(C6H5)2)3)Ni(CS2) (60294-99-7)

Guidance literature:

With NaBH₄; In ethanol; acetone; (N2); soln. of NaBH4 in EtOH added dropwise to Ni complex suspn. in acetone; EtOH added; elem. anal.;

Reference yield: 70.0%

[(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S2CNEt2)]BPh4 (83561-99-3) → (CH3C(CH2P(C6H5)2)3)Ni(CS2) (60294-99-7) + (CH3C(CH2P(C6H5)2)3)Ni(S2CS) (83562-00-9)

Guidance literature:

With NaBH₄; CS₂; In ethanol; acetone; soln. of Ni-complex in acetone was treated with NaBH4 in EtOH, CS2 was added, BuOH was added;

Reference yield:

(CH3C(CH2P(C6H5)2)3)Ni(S2CS) (83562-00-9) → (CH3C(CH2P(C6H5)2)3)Ni(CS2) (60294-99-7)

Guidance literature:

Multi-step reaction with 3 steps

1: ethanol; dichloromethane

2: dichloromethane

3: NaBH₄; CS₂ / ethanol; acetone

With NaBH₄; CS₂; In ethanol; dichloromethane; acetone;

upstream raw materials:

Ni(CO)CH₃C{CH₂P(C₆H₅)2}3

[(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S₂CSMe)]BPh₄

[(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S₂CNEt₂)]BPh₄

(CH₃C(CH₂P(C₆H₅)2)3)Ni(S₂CS)

Downstream raw materials:

Ni(CO)CH₃C{CH₂P(C₆H₅)2}3

(CH₃C(CH₂P(C₆H₅)2)3)Ni(SCN(C₆H₅))*0.5CH₂Cl₂

{OP(C₆H₅)2CH₂C(CH₃)(CH₂P(C₆H₅)2)2}Ni(CO₃)*0.5H₂O*C₆H₆

{OP(C₆H₅)2CH₂C(CH₃)(CH₂P(C₆H₅)2)2}Ni(CO₃)