o-chlorophenylmethylphenylsilane

Base Information

• Chemical Name: o-chlorophenylmethylphenylsilane
• CAS No.: 18081-04-4
• Molecular Formula: C₁₃H₁₃ClSi
• Molecular Weight: 232.785
• Mol file: 18081-04-4.mol

Synonyms:o-chlorophenylmethylphenylsilane

Chemical Property of o-chlorophenylmethylphenylsilane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of o-chlorophenylmethylphenylsilane

There total 2 articles about o-chlorophenylmethylphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

2-iodochlorobenzene (615-41-8) + chloro(methyl)phenylsilane (1631-82-9) → o-chlorophenylmethylphenylsilane (18081-04-4) + bis(phenyl methyl hydrido)disiloxane (6689-22-1)

Guidance literature:

2-iodochlorobenzene; With TurboGrignard; In tetrahydrofuran; 1,2-dimethoxyethane; at -20 ℃; Inert atmosphere;

chloro(methyl)phenylsilane; With N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; 1,2-dimethoxyethane; at -20 - 20 ℃; Inert atmosphere;

With water; ammonium chloride; In tetrahydrofuran; 1,2-dimethoxyethane; Inert atmosphere;

DOI:10.1021/jo802433t

Reference yield:

→ o-chlorophenylmethylphenylsilane (18081-04-4)

Guidance literature:

Phenyl-<2-chlor-phenyl>-silan, Methyl-magnesiumiodid, THF, Δ;

DOI:10.1021/jo01052a086

Reference yield:

o-chlorophenylmethylphenylsilane (18081-04-4) → 5,10-dimethyl-5,10-diphenyl-5,10-dihydro-silanthrene (18840-15-8)

Guidance literature:

With sodium; In toluene;

DOI:10.1021/jo01052a086

upstream raw materials:

2-iodochlorobenzene

chloro(methyl)phenylsilane

Downstream raw materials:

5,10-dimethyl-5,10-diphenyl-5,10-dihydro-silanthrene

Refernces