(1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-sulfinyldioxybicyclo<3.1.0>hexane

Base Information

Chemical Name:(1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-sulfinyldioxybicyclo<3.1.0>hexane
CAS No.:199122-49-1
Molecular Formula:C₂₂H₂₄O₅S
Molecular Weight:400.496
Hs Code.:

Synonyms:(1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-sulfinyldioxybicyclo<3.1.0>hexane

Suppliers and Price of (1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-sulfinyldioxybicyclo<3.1.0>hexane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-sulfinyldioxybicyclo<3.1.0>hexane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-sulfinyldioxybicyclo<3.1.0>hexane

There total 6 articles about (1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-sulfinyldioxybicyclo<3.1.0>hexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 199122-46-8
(1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-dihydroxybicyclo<3.1.0>hexane

: 199122-49-1
(1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-sulfinyldioxybicyclo<3.1.0>hexane

Guidance literature:: With thionyl chloride; triethylamine; at 0 ℃; for 0.05h;
DOI:10.1016/0040-4039(96)00289-4

Reference yield:

: 199122-34-4
(1R,3R,4S,5S)-1-<(benzyloxy)methyl>-3,4-(isopropylidenedioxy)-2-oxo-bicyclo<3.1.0>hexane

: 199122-49-1
(1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-sulfinyldioxybicyclo<3.1.0>hexane

Guidance literature:: Multi-step reaction with 5 steps

1: 90 percent / n-BuLi / hexane; tetrahydrofuran / 0.5 h / 0 °C

2: 90 percent / BH₃*THF, NaBO₃*H₂O / tetrahydrofuran / 16 h / 0 - 20 °C

3: 88 percent / NaH, n-Bu₄NI / tetrahydrofuran / 15 h / Heating

4: 100 percent / aq. HCl / tetrahydrofuran; methanol / 10 h / Heating

5: 80 percent / SOCl₂, Et₃N / CH₂Cl₂ / 0.08 h / 0 °C

With hydrogenchloride; sodium perborate; n-butyllithium; thionyl chloride; borane-THF; tetra-(n-butyl)ammonium iodide; sodium hydride; triethylamine; In tetrahydrofuran; methanol; hexane; dichloromethane;
DOI:10.1021/jo990010m

Reference yield:

: 199122-43-5
1,2-dibenzyloxymethyl-3,4-(isopropylidenedioxy)bicyclo<3.1.0>hexane

: 199122-49-1
(1S,2S,3R,4S,5S)-1,2-di<(benzyloxy)methyl>-3,4-sulfinyldioxybicyclo<3.1.0>hexane

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / aq. HCl / tetrahydrofuran; methanol / 10 h / Heating

2: 80 percent / SOCl₂, Et₃N / CH₂Cl₂ / 0.08 h / 0 °C

With hydrogenchloride; thionyl chloride; triethylamine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/jo990010m